One-pot three-component synthesis of α-methylated ketones from secondary and primary aryl alcohols
Literature Information
Publication Date
2023-12-05
DOI
10.1039/D3NJ05498E
Impact Factor
3.591
Authors
Shaikh Samser, Priyabrata Biswal, Omkar Mohapatra, Sanu Siyad Pullarat, Sushanta Kumar Meher, Krishnan Venkatasubbaiah
View Original
Abstract
One-pot three-component synthesis of α-methylated ketones from secondary and primary alcohols via a triple dehydrogenative method is presented here. This protocol uses a polystyrene-supported catalyst and the catalyst is reused for five runs without any drop in its activity. Detailed mechanistic investigation was carried out with control reactions and deuterium labelling experiments revealed that secondary and primary alcohols act as a hydrogen source in this one-pot synthesis of α-methylated substituted ketones.
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Source Journal
New Journal of Chemistry
CiteScore:
5.3
Self-citation Rate:
3.7%
Articles per Year:
2153
NJC (New Journal of Chemistry) is a broad-based primary journal encompassing all branches of chemistry and its sub-disciplines. It contains full research articles, communications, perspectives and focus articles. This well-established journal, owned by the Centre National de la Recherche Scientifique (CNRS) of France, has been co-published with the Royal Society of Chemistry since January 1998. NJC is the forum for the publication of high-quality, original and significant work that opens new directions in chemistry or other scientific disciplines. In addition to having a significant chemical component, work published in NJC must demonstrate that it will have an impact on areas of research other than that of the reported work.
Recommended Compounds
![2,2'-{2,2-Propanediylbis[(2,6-dibromo-4,1-phenylene)oxy]}diethanol structure](https://static.chemtradehub.com/structs/416/4162-45-2-b3d6.webp "2,2'-{2,2-Propanediylbis[(2,6-dibromo-4,1-phenylene)oxy]}diethanol structure")
2,2'-{2,2-Propanediylbis[(2,6-dibromo-4,1-phenylene)oxy]}diethanol
CAS Number:
4162-45-2
Molecular Formula:
C19H20Br4O4
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