The photoinduced long-lived charge-separated state of Ru(bpy)3–methylviologen with cucurbit[8]uril in aqueous solution

Literature Information

Publication Date 2006-08-24
DOI 10.1039/B609015J
Impact Factor 6.222
Authors

Shiguo Sun, Rong Zhang, Samir Andersson, Jingxi Pan, Björn Åkermark, Licheng Sun


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Abstract

A stable 1 : 1 inclusion complex of Ru(bpy)3–MV2+ with cucurbit[8]uril (CB[8]) is formed in aqueous solution; upon light irradiation, a long lived (τ ∼ 2 µs) charge-separated state Ru3+–MV+˙–CB[8] is observed.

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