Inherent helicity in an extended tris-bipyridyl molecular cage

Literature Information

Publication Date 2003-11-20
DOI 10.1039/B312716H
Impact Factor 6.222
Authors

David F. Perkins, Leonard F. Lindoy, George V. Meehan, Peter Turner


View Original

Abstract

A new molecular cage incorporating three bipyridyl units has been synthesised by a conventional multi-step procedure as well as, much more efficiently, by a Ni(II) template procedure; an X-ray structure of the nickel complex shows that it adopts an exo configuration of each of the bridgehead nitrogen lone pairs, the central metal ion acts to promote a triple helical twist that extends ∼22 Å along the axial length of the molecule.

Related Literature

Anomalous high photovoltages observed in shish kebab-like organic p–n junction nanostructures

Daniel L. Jacobs, Benjamin R. Bunes, Helin Huang, Xiaomei Yang, Ling Zang

2013-08-30 Communication

DOI: 10.1039/C3PY01026K

One pot synthesis and characterization of novel poly(ether ester) mutiblock copolymers containing poly(tetramethylene oxide) and poly(ethylene terephthalate)

Weichun Huang, Yingbo Wan, Jianying Chen, Qiaozhen Xu, Xiaohong Li, Xiaoming Yang, Yaowen Li, Yingfeng Tu

2013-10-18 Paper

DOI: 10.1039/C3PY00932G

Precise evaluation of the block copolymer nanoparticle growth in polymerization-induced self-assembly under dispersion conditions

Yang Su, Xin Xiao, Shentong Li, Meihan Dan, Xiaohui Wang, Wangqing Zhang

2013-08-30 Paper

DOI: 10.1039/C3PY00995E

Combining surface topography with polymer chemistry: exploring new interfacial biological phenomena

Dan Li, Qing Zheng, Yanwei Wang, Hong Chen

2013-07-29 Review Article

DOI: 10.1039/C3PY00739A

One-step synthesis of polypyrazoles and self-assembled polypyrazole–copper catalysts for click chemistry

Longqiang Xiao, Shaojun Cai, Qingye Liu, Liqiong Liao, Xin Guo, Yan Li, Xiangxiang Jia, Feifei Li, Lijian Liu

2013-09-03 Paper

DOI: 10.1039/C3PY01105D

Photosensitizer-conjugated redox-responsive dextran theranostic nanoparticles for near-infrared cancer imaging and photodynamic therapy

Peng Liu, Caixia Yue, Zonghai Sheng, Guanhui Gao, Mingxing Li, Huqiang Yi, Cuifang Zheng, Bi Wang, Lintao Cai

2013-09-20 Paper

DOI: 10.1039/C3PY01173A

Fabrication of aggregation induced emission dye-based fluorescent organic nanoparticles via emulsion polymerization and their cell imaging applications

Xiqi Zhang, Bin Yang, Meiying Liu, Wanyun Liu, Yiwang Chen, Yen Wei

2013-08-20 Paper

DOI: 10.1039/C3PY00984J

Synthesis and solid state helix to helix rearrangement of poly(phenylacetylene) bearing n-octyl alkyl side chains

Asahi Motoshige, Yoshiaki Yoshida, Ranko Motoshige

2013-09-26 Paper

DOI: 10.1039/C3PY01000G

You might also like

Compound Q&A

What are the main uses of 1H-Indazole-6-carbonitrile (CAS: 141290-59-7)?

1H-Indazole-6-carbonitrile finds applications in pharmaceuticals, where it serve...

141290-59-71H-Indazole-6-carbon...
Compound Q&A

How should waste containing Dioctyl (2E)-2-butenedioate (CAS: 2997-85-5) be handled?

Waste containing Dioctyl (2E)-2-butenedioate (CAS: 2997-85-5) should be collecte...

2997-85-5Dioctyl (2E)-2-buten...
Compound Q&A

What industries use Sodium [(1,2-benzoxazol-3-ylmethyl)sulfonyl]azanide (CAS: 68291-98-5)?

Sodium [(1,2-benzoxazol-3-ylmethyl)sulfonyl]azanide is primarily used in pharmac...

68291-98-5Sodium [(1,2-benzoxa...
Compound Q&A

Are there alternatives to Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,6-pyridinedicarboxylate (CAS: 741709-66-0) in synthesis?

Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,6-pyridinedicarboxyla...

741709-66-0Dimethyl 4-(4,4,5,5-...
Compound Q&A

How should waste containing 2-Fluoro-6-hydrazinopyridine (CAS: 80714-39-2) be handled?

Waste containing 2-Fluoro-6-hydrazinopyridine (CAS: 80714-39-2) should be manage...

80714-39-22-Fluoro-6-hydrazino...
Compound Q&A

What is 6-Formyl-2-pyridinecarboxylic acid (CAS: 499214-11-8)?

6-Formyl-2-pyridinecarboxylic acid is an organic compound with the molecular for...

499214-11-86-Formyl-2-pyridinec...
900874-91-13-(3,4-dimethoxyphen...
Compound Q&A

How is 9H-Tribenzo[b,d,f]azepine (CAS: 29875-73-8) typically synthesized?

9H-Tribenzo[b,d,f]azepine is typically synthesized via a multi-step process invo...

29875-73-89H-Tribenzo[b,d,f]az...
Compound Q&A

How is 1-Cyclopropyl-7-ethoxy-6-fluoro-8-methoxy-4-oxo-1,4-dihydro-3-quinolinecarboxylic acid (CAS: 1797982-51-4) typically synthesized?

1-Cyclopropyl-7-ethoxy-6-fluoro-8-methoxy-4-oxo-1,4-dihydro-3-quinolinecarboxyli...

1797982-51-41-Cyclopropyl-7-etho...
Compound Q&A

How should waste containing Methyl 3-oxo-1,2,3,4-tetrahydro-6-quinoxalinecarboxylate (CAS: 671820-52-3) be handled?

Waste containing Methyl 3-oxo-1,2,3,4-tetrahydro-6-quinoxalinecarboxylate (CAS: ...

671820-52-3Methyl 3-oxo-1,2,3,4...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.