Fast, long-range electron-transfer reactions of a ‘blue’ copper protein coupled non-covalently to an electrode through a stilbenyl thiolate monolayer
Literature Information
Publication Date
2004-01-07
DOI
10.1039/B312936E
Impact Factor
6.222
Authors
Paul L. Burn, Graham R. Webster
View Original
Abstract
A self-assembled monolayer (SAM), formed by the insitu saponification of a stilbenyl thioacetate on a gold electrode, yields fast electron transfer (ET) (the exchange rate at zero driving force exceeds 1600 s−1) with adsorbed molecules of the ‘blue’ copper protein, azurin, over a distance exceeding 15 Å.
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