VIII(OH){O2C–C6H4–CO2}.(HO2C–C6H4–CO2H)x(DMF)y(H2O)z (or MIL-68), a new vanadocarboxylate with a large pore hybrid topology : reticular synthesis with infinite inorganic building blocks?

Literature Information

Publication Date 2004-02-05
DOI 10.1039/B312589K
Impact Factor 6.222
Authors

K. Barthelet, J. Marrot, G. Férey, D. Riou


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Abstract

VIII(OH){O2C–C6H4–CO2}.(HO2C–C6H4–O2H)x(DMF)y(H2O)z or MIL-68 was solvothermally synthesised in a non-aqueous medium. Its structure, built up from octahedral chains connected by terephthalate linkers, exhibits large hexagonal channels containing different occluded moieties. Their irreversible removal releases a specific surface area of 603(22) m2.g−1 (BET).

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