Enantioselective synthesis of α-terpineol and nephthenol by intramolecular acyloxazolidinone enolate alkylations

Literature Information

Publication Date 2006-06-02
DOI 10.1039/B605346G
Impact Factor 6.222
Authors

Yinghua Jin, Robert M. Coates


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Abstract

Enolate anions generated from norterpenyl bromides bearing oxazolidinone chiral auxiliaries at the chain termini underwent efficient, stereo-biased cyclizations to form 6- and 14-membered rings in novel synthetic routes to α-terpineol and nephthenol enantiomers.

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