Intramolecular charge-transfer fluorescence of 1-phenyltridecamethylbicyclo[2.2.2]octasilane
Literature Information
Publication Date
2005-08-23
DOI
10.1039/B505109F
Impact Factor
6.222
Authors
Wataru Setaka, Natsuki Hamada, Chizuko Kabuto, Mitsuo Kira
View Original
Abstract
1-Phenyltridecamethylbicyclo[2.2.2]octasilane (1) is prepared by the reaction of the corresponding 1-chlorotridecamethylbicyclo[2.2.2]octasilane with phenyllithium in the presence of N,N,N′,N′-tetramethylethylenediamine and the molecular structure of 1 is determined by X-ray crystallography. Phenyloligosilane 1 shows dual fluorescence even in non-polar hexane though the TICT-like mechanism is not applicable.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
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Ethyl 3-((6-(4,5-dihydro-1H-benzo[d]azepin-3(2H)-yl)-2-(pyridin-2-yl)pyrimidin-4-yl)amino)propanoate
CAS Number:
1373423-53-0
Molecular Formula:
C24H27N5O2
![N-[(9H-Fluoren-9-ylmethoxy)carbonyl]-beta-phenyl-L-phenylalanine structure](https://static.chemtradehub.com/structs/201/201484-50-6-c2fc.webp "N-[(9H-Fluoren-9-ylmethoxy)carbonyl]-beta-phenyl-L-phenylalanine structure")
N-[(9H-Fluoren-9-ylmethoxy)carbonyl]-beta-phenyl-L-phenylalanine
CAS Number:
201484-50-6
Molecular Formula:
C30H25NO4
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N,N'-1,2-Ethanediylbis[2-(vinylsulfonyl)acetamide]
CAS Number:
66710-66-5
Molecular Formula:
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