Rational design of a graphitic carbon nitride catalytic–biocatalytic system as a photocatalytic platform for solar fine chemical production from CO2

Literature Information

Publication Date 2022-04-06
DOI 10.1039/D2RE00079B
Impact Factor 4.239
Authors

Satyam Singh, Rajesh K. Yadav, Tae Wu Kim, Chandani Singh, Pooja Singh, Atul P. Singh, Alok Kumar Singh, Atresh Kumar Singh, Jin-Ook Baeg, Sarvesh Kumar Gupta


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Abstract

We report that generating (formic acid) and regenerating (NADH/NADPH) from CO2 and NAD+/NADP+ using a nitrogen-rich polymeric carbon nitride catalytic–biocatalytic system under solar light (λ > 420 nm) could provide a new approach for storage of clean energy. In situ thermally copolymerized urea along with a 1,4-diaminoanthraquinone (AQ) monomer using a modified carbon nitride (CN) photocatalyst (AQBCN) was undertaken. The artificial AQBCN photocatalyst–biocatalyst system led to formic acid (344.12 μmol) generation and NADH/NADPH regeneration (97.21/95%) in comparison with monomers. Our method could be employed to develop an AQBCN photocatalyst for selective regeneration of NADH/NADPH and CO2 generation.

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Source Journal

Reaction Chemistry & Engineering

Reaction Chemistry & Engineering
CiteScore: 0
Self-citation Rate: 8.8%
Articles per Year: 284

Reaction Chemistry & Engineering is an interdisciplinary journal reporting cutting-edge research focused on enhancing the understanding and efficiency of reactions. Reaction engineering leverages the interface where fundamental molecular chemistry meets chemical engineering and technology. Challenges in chemistry can be overcome by the application of new technologies, while engineers may find improved solutions for process development from the latest developments in reaction chemistry. Reaction Chemistry & Engineering is a unique forum for researchers whose interests span the broad areas of chemical engineering and chemical sciences to come together in solving problems of importance to wider society. All papers should be written to be approachable by readers across the engineering and chemical sciences. Papers that consider multiple scales, from the laboratory up to and including plant scale, are particularly encouraged.

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