Solvent-free ketone hydrogenations catalyzed by molybdenum complexes

Literature Information

Publication Date 2004-03-22
DOI 10.1039/B401760A
Impact Factor 6.222
Authors

Barbara F. M. Kimmich, Paul J. Fagan, Elisabeth Hauptman, R. Morris Bullock


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Abstract

Et2CO is hydrogenated under solvent-free conditions using a catalyst prepared by hydride abstraction from HMo(CO)2[η5:η1-C5H4(CH2)2PCy2]; the catalyst functions at low catalyst loadings (<0.4 mol%).

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