Solvent-free ketone hydrogenations catalyzed by molybdenum complexes
Literature Information
Barbara F. M. Kimmich, Paul J. Fagan, Elisabeth Hauptman, R. Morris Bullock
Et2CO is hydrogenated under solvent-free conditions using a catalyst prepared by hydride abstraction from HMo(CO)2[η5:η1-C5H4(CH2)2PCy2]; the catalyst functions at low catalyst loadings (<0.4 mol%).
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![(2R,6S)-6-[(Benzyloxy)methyl]-4-{[(2-methyl-2-propanyl)oxy]carbonyl}-2-morpholinecarboxylic acid structure (2R,6S)-6-[(Benzyloxy)methyl]-4-{[(2-methyl-2-propanyl)oxy]carbonyl}-2-morpholinecarboxylic acid structure](https://static.chemtradehub.com/structs/109/1093085-91-6-3382.webp)
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