Synthesis and structure of [Na11(OtBu)10(OH)]: 1H NMR shift of a hydroxide ion encapsulated in a 21-vertex alcoholate cage

Literature Information

Publication Date 2003-10-17
DOI 10.1039/B308105B
Impact Factor 6.222
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Abstract

[Na11(OtBu)10(OH)], a hydroxide enclosing 21-vertex cage compound, was found to crystallize from mixtures of sodium tert.butanolate with sodium hydroxide. Its structure can be derived from the known (NaOtBu)6-hexaprismane by replacing one butanolate unit with OH− and capping the latter with five additional units of NaOtBu. The hydroxide shows a signal at −3.21 ppm in the 1H NMR spectrum.

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