[{AuTl(C6Cl5)2(toluene)}2(dioxane)]: A striking structure that leads to a blue luminescence

Literature Information

Publication Date 2003-06-16
DOI 10.1039/B304835G
Impact Factor 6.222
Authors

Eduardo J. Fernández, Antonio Laguna, José María López-de-Luzuriaga, M. Elena Olmos, Javier Pérez


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Abstract

The complex [{AuTl(C6Cl5)2(toluene)}2(dioxane)] displays a structure with the thallium(I) center in an unprecedented trigonal planar environment, showing the shortest Au–Tl interaction ever found, a toluene molecule in a η6-mode and the “disappearance” of the Tl(I) inert pair, usually stereochemically active. These characteristics are responsible for its unusual luminescent behaviour.

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