[{AuTl(C6Cl5)2(toluene)}2(dioxane)]: A striking structure that leads to a blue luminescence
Literature Information
Eduardo J. Fernández, Antonio Laguna, José María López-de-Luzuriaga, M. Elena Olmos, Javier Pérez
The complex [{AuTl(C6Cl5)2(toluene)}2(dioxane)] displays a structure with the thallium(I) center in an unprecedented trigonal planar environment, showing the shortest Au–Tl interaction ever found, a toluene molecule in a η6-mode and the “disappearance” of the Tl(I) inert pair, usually stereochemically active. These characteristics are responsible for its unusual luminescent behaviour.
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