First example of electrophile induced Baylis–Hillman reaction: a novel facile one-pot synthesis of indolizine derivatives

Literature Information

Publication Date 2003-02-17
DOI 10.1039/B211349J
Impact Factor 6.222
Authors

Deevi Basavaiah, Anumolu Jaganmohan Rao


View Original

Abstract

Treatment of pyridine-2-carboxaldehyde with activated alkenes such as alkyl vinyl ketones and cyclic enones in the presence of trimethylsilyl trifluoromethanesulfonate (TMSOTf) provides a novel facile one-pot synthesis of indolizine derivatives, thus for the first time describing an electrophile induced Baylis–Hillman reaction.

Related Literature

Energy landscape of Au13: a global view of structure transformation

Xiao-Tian Li, Shao-Gang Xu

2020-01-27 Paper

DOI: 10.1039/C9CP06463J

Contents list

Front/Back Matter

DOI: 10.1039/D0CP90038A

Interfacial structure in the liquid–liquid extraction of rare earth elements by phosphoric acid ligands: a molecular dynamics study

Balarama Sridhar Dwadasi, Sriram Goverapet Srinivasan, Beena Rai

2020-02-05 Paper

DOI: 10.1039/C9CP05719F

Biological control of S-nitrosothiol reactivity: potential role of sigma-hole interactions

Niloufar Hendinejad, Qadir K. Timerghazin

2020-03-02 Paper

DOI: 10.1039/C9CP06377C

Growth and auto-oxidation of Pd on single-layer AgOx/Ag(111)

Vikram Mehar, Christopher R. O’Connor, Mustafa Karatok, Robert J. Madix, Jason F. Weaver

2020-02-25 Paper

DOI: 10.1039/C9CP06973A

Electronic structure, doping effect and topological signature in realistic intermetallics Li3−xNaxM (x = 3, 2, 1, 0; M = N, P, As, Sb, Bi)

Lei Jin, Xiaoming Zhang, Tingli He, Weizhen Meng, Xuefang Dai, Guodong Liu

2020-02-28 Paper

DOI: 10.1039/C9CP06033B

Co-deposition of gas hydrates by pressurized thermal evaporation

Alexander Ostermann, Tobias M. Gasser, Thomas Loerting, Jörg Petrasch

2020-02-11 Paper

DOI: 10.1039/C9CP04735B

Interaction of hydantoin with solar wind minority ions: O6+ and He2+

Julie Renoud, Suvasthika Indrajith, Alicja Domaracka, Patrick Rousseau, Patrick Moretto-Capelle, Bernd A. Huber, Jean-Philippe Champeaux

2020-01-28 Paper

DOI: 10.1039/C9CP06230K

Phonon and magnetoelastic coupling in Al0.5Ga0.5FeO3: Raman, magnetization and neutron diffraction studies

K. K. Mishra, R. Shukla, P. S. R. Krishna, P. D. Babu, S. N. Achary, R. S. Katiyar

2020-03-03 Paper

DOI: 10.1039/C9CP06124J

Triplet fusion upconversion using sterically protected 9,10-diphenylanthracene as the emitter

Can Gao, Bolong Zhang, Christopher R. Hall, Li Li, Yeqin Chen, Yi Zeng, Trevor A. Smith, Wallace W. H. Wong

2020-02-26 Paper

DOI: 10.1039/C9CP06311K

You might also like

Compound Q&A

What precautions should be taken when handling lithium chloride hydrate (1:1:1) (CAS: 16712-20-2)?

When handling lithium chloride hydrate (1:1:1) (CAS: 16712-20-2), it is importan...

16712-20-2Lithium chloride hyd...
Compound Q&A

Is 4-(4H-1,2,4-Triazol-4-yl)piperidine (CAS: 690261-92-8) safe?

4-(4H-1,2,4-Triazol-4-yl)piperidine is generally considered safe for use in phar...

690261-92-84-(4H-1,2,4-Triazol-...
Compound Q&A

How should waste containing 1,3-Thiazole-2-carboxamide (CAS: 16733-85-0) be handled?

Waste containing 1,3-Thiazole-2-carboxamide (CAS: 16733-85-0) should be collecte...

16733-85-01,3-Thiazole-2-carbo...
Compound Q&A

What regulatory guidelines apply to 5-(Difluoromethyl)-2-fluorobenzonitrile (CAS: 934175-58-3)?

5-(Difluoromethyl)-2-fluorobenzonitrile (CAS: 934175-58-3) is subject to regulat...

934175-58-35-(Difluoromethyl)-2...
Compound Q&A

How is Methyl 3-acetamido-2-thiophenecarboxylate (CAS: 22288-79-5) typically synthesized?

Methyl 3-acetamido-2-thiophenecarboxylate can be synthesized by the reaction of ...

22288-79-5Methyl 3-acetamido-2...
Compound Q&A

What is 4-Isoquinolinecarbonitrile (CAS: 34846-65-6)?

4-Isoquinolinecarbonitrile is a chemical compound with the CAS number 34846-65-6...

34846-65-64-Isoquinolinecarbon...
Compound Q&A

How should Methyl 1H-1,2,3-triazole-4-carboxylate (CAS: 877309-59-6) be stored?

Store Methyl 1H-1,2,3-triazole-4-carboxylate (CAS: 877309-59-6) in a cool, dry p...

877309-59-6Methyl 1H-1,2,3-tria...
Compound Q&A

What regulatory guidelines apply to 6-Bromo[1,3]thiazolo[5,4-b]pyridin-2-amine (CAS: 1160791-13-8)?

6-Bromo[1,3]thiazolo[5,4-b]pyridin-2-amine (CAS: 1160791-13-8) is subject to the...

1160791-13-86-Bromo[1,3]thiazolo...
Compound Q&A

Is (2S,3S)-2-Ammonio-3-(3,4-dihydroxyphenyl)-3-hydroxypropanoate (CAS: 23651-95-8) safe?

(2S,3S)-2-Ammonio-3-(3,4-dihydroxyphenyl)-3-hydroxypropanoate (CAS: 23651-95-8) ...

23651-95-8(2S,3S)-2-Ammonio-3-...
Compound Q&A

What are the physical and chemical properties of 7-bromo-3-methyl-3,4-dihydroquinazolin-4-one (CAS: 1293987-84-4)?

7-Bromo-3-methyl-3,4-dihydroquinazolin-4-one is a solid with a crystalline form....

1293987-84-47-bromo-3-methyl-3,4...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.