(s)-Di-(3s,5s,7s)-adamantan-1-yl(benzyl)phosphine

Basic Information

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CAS Number

395116-70-8

Molecular Formula

C27H37P

Molecular Weight

392.57 g/mol

Chemical Classification

Agricultural Chemicals Pesticides Insecticides

Basic Physical Properties

Melting Point

183°C

SMILES

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C1C2CC3CC1CC(C2)(C3)P(CC4=CC=CC=C4)C56CC7CC(C5)CC(C7)C6

InChI

InChI=1S/C27H37P/c1-2-4-19(5-3-1)18-28(26-12-20-6-21(13-26)8-22(7-20)14-26)27-15-23-9-24(16-27)11-25(10-23)17-27/h1-5,20-25H,6-18H2/t20-,21+,22-,23-,24+,25-,26-,27-

InChIKey

ANIAFEJRWQDKDV-ANIFQACUSA-N

LogP

7.606100000000008

Topological Polar Surface Area

0.0 Å²

Hydrogen Bond Donor/Acceptor

0 / 0

Complexity

487

Safety Information

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Sensitiveness

air sensitive

Synonyms & References

English

C27H37P
DI(1-ADAMANTYL)BENZYLPHOSPHINE
Di(adamantan-1-yl)(benzyl)phosphine
bis(1-adamantyl)-benzylphosphane
MFCD05861603
DTXSID90460735
395116-70-8
AKOS015900190
2,2-[[3-acetamido-4-[(4-nitrophenyl)azo]phenyl]imino]diethyldiacetate
I11992
AMY11682
SCHEMBL289717
benzyl(di-adamantyl)phosphine
Di-1-adamantylbenzylphosphine
A873640
Di(1-adamantyl)benzylphosphine, 95%
Di(1-adamantyl)(benzyl)phosphine
FT-0689976
Benzyldi(tricyclo[3.3.1.1~3,7~]decan-1-yl)phosphane
BENZYLDI-1-ADAMANTYLPHOSPHINE
BP-12234
VQA11670
SY033518
CS-W011722
J-519829
BCP21867
Di(1-adamantyl)benzylphosphine
Benzyldi-1-adamantylphosphine
Benzyldi-1-adaMantylphosphine [cataCXiuM? ABn]
Phosphine,(phenylmethyl)bis(tricyclo[3.3.1.13,7]dec-1-yl)-
CATACXIUM ABN

MDL Number

MFCD05861603

Customs Code

2931900090

FAQ

What are the physical and chemical properties of (s)-Di-(3s,5s,7s)-adamantan-1-yl(benzyl)phosphine (CAS: 395116-70-8)?

The compound (s)-Di-(3s,5s,7s)-adamantan-1-yl(benzyl)phosphine is an organophosphine with a crystalline form. Its molecular weight is approximately 511.7 g/mol. This compound has limited water solubility, making it suitable for organic synthesis. It is known for its reactivity in coordination chemistry and as a ligand in transition metal complexes. It is typically used in high purity and handled under inert conditions to avoid degradation.

How is (s)-Di-(3s,5s,7s)-adamantan-1-yl(benzyl)phosphine (CAS: 395116-70-8) typically synthesized?

The compound (s)-Di-(3s,5s,7s)-adamantan-1-yl(benzyl)phosphine is synthesized through a multi-step process involving the condensation of phosphorus trichloride with the corresponding 3,5,7-trisubstituted adamantane and benzyl alcohol. The reactions are typically carried out under an inert atmosphere to prevent decomposition. The yield and selectivity can be enhanced using catalytic amounts of Lewis acids or bases.

What industries use (s)-Di-(3s,5s,7s)-adamantan-1-yl(benzyl)phosphine (CAS: 395116-70-8)?

The (s)-Di-(3s,5s,7s)-adamantan-1-yl(benzyl)phosphine is widely used in the pharmaceutical, polymer, and semiconductor industries. It serves as a key ligand in the development of new materials and catalytic systems. In pharmaceuticals, it plays a role in the synthesis of complex organic molecules. In polymers, it acts as a monomer modifier, and in semiconductors, it is used in the doping process.

What precautions should be taken when handling (s)-Di-(3s,5s,7s)-adamantan-1-yl(benzyl)phosphine (CAS: 395116-70-8)?

When handling (s)-Di-(3s,5s,7s)-adamantan-1-yl(benzyl)phosphine, it is essential to wear appropriate personal protective equipment (PPE) such as gloves, safety goggles, and lab coats. Work should be performed in a fume hood to minimize exposure. Spills should be cleaned up immediately using an appropriate solvent. Always refer to the Safety Data Sheet (SDS) for detailed handling and disposal instructions. The compound should be stored in a cool, dry place away from direct sunlight and ignition sources.