[1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichloro-[(2-isopropoxyphenyl)methylene]ruthenium

Basic Information

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CAS Number

301224-40-8

Molecular Formula

C31H38Cl2N2ORu

Molecular Weight

626.62 g/mol

Chemical Classification

Basic Chemical Raw Materials Organic Chemicals Ethers

Basic Chemical Raw Materials Organic Chemicals Heterocyclic Compounds

Pharmaceutical Chemicals Pharmaceutical Intermediates Heterocyclic Intermediates

Fine Chemicals Dyes and Pigments Organic Dyes

Agricultural Chemicals Pesticides Herbicides

Laboratory Chemicals Research Chemicals Biochemical Reagents

Basic Physical Properties

Melting Point

216-220 °C

Boiling Point

No data available

Flash Point

No data available

Vapor Pressure

No data available

SMILES

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CC(OC1=CC=CC=C1C=[Ru+2]=C2N(C3=C(C)C=C(C)C=C3C)CCN2C4=C(C)C=C(C)C=C4C)C.[Cl-].[Cl-]

InChI

InChI=1S/C21H26N2.C10H11O.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-8(2)11-10-7-5-4-6-9(10)3;;;/h9-12H,7-8H2,1-6H3;4-8H,1-2H3;2*1H;/q2*-2;;;+6/p-2

InChIKey

ZRPFJAPZDXQHSM-UHFFFAOYSA-L

LogP

8.18270

Complexity

828

Safety Information

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Hazard Statement

H315 Causes skin irritation
Skin corrosion/irritation

H319 Causes serious eye irritation
Serious eye damage/eye irritation

H335 May cause respiratory irritation
Specific target organ toxicity, single exposure; Respiratory tract irritation

Sensitiveness

对光和空气敏感

Synonyms & References

English

(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM
HOVEYDA-GRUBBS CATALYST
RUTHENIUM,[1,3-BIS(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE]DICHLORO[[2-(1-METHYLETHOXY)PHENYL]METHYLENE]
Hoveyda-Grubbs Catalyst 2nd Generation
Hoveyda-Grubbs Catalyst 2nd
[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(2-isopropoxyphenylmethylene)ruthenium
Hoveyda-Grubbs Catalyst 2nd Generation,(1,3-Bis-(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(o-isopropoxyphenylmethylene)ruthenium
(1,3-Bis-(2,4,6-triMethylphenyl)-2-iMidazolidinylidene)dichloro (o-isopropylphenylMethylene)rutheniuM
(1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI) chloride
(1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxy-benzylidene)ruthenium(VI) chloride
[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene] Dichloro(o-isopropoxyphenylmethylene)ruthenium
[1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichloro-[(2-propan-2-yloxyphenyl)methylidene]ruthenium
HOVEYDA GRUBBS II GENRATION CATALYST
Ruthenium,[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy-kO)phenyl]methylene-kC]-, (...
Ruthenium,[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy-kO)phenyl]methylene-kC]-, (SP-5-4
Ruthenium,[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy-kO)phenyl]methylene-kC]-, (SP-5-41)-
Ruthenium,[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy-kO...
Grubbs-Hoveyda second generationpre-catalyst
HOVEYDA-GRUBBS 2ND GENERATION
Hoveyda-Grubbs catalyst second-generation catalyst
IHMes-o-isopropoxybenzylidene-ruthenium dichloride
Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene](2-isopropoxyphenylmethylene)ruthenium(II)
Grubbs Catalyst® C627
[1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichloro-[(2-isopropoxyphenyl)methylene]ruthenium

MDL Number

MFCD03701614

Customs Code

2933990090

FAQ

What are the physical and chemical properties of (1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene)-dichloro-[(2-isopropoxyphenyl)methylene]ruthenium (CAS: 301224-40-8)?

The compound has a crystalline form with a molecular weight of approximately 856.09 g/mol. It is poorly soluble in common organic solvents. The compound shows moderate reactivity, particularly towards reducing agents. It can undergo thermal decomposition and is known to form complexes with ruthenium, exhibiting unique spectroscopic and catalytic properties.

How is (1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene)-dichloro-[(2-isopropoxyphenyl)methylene]ruthenium (CAS: 301224-40-8) typically synthesized?

The compound is typically synthesized through a multistep process involving the reaction of ruthenium(II) chloride with 1,3-bis(2,4,6-trimethylphenyl)imidazolidine-2-thione and 2-isopropoxybenzaldehyde. The synthesis requires an inert atmosphere and is conducted in a solvent like toluene. The yield is around 80%, and the reaction is highly selective towards the desired product.

What industries use (1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene)-dichloro-[(2-isopropoxyphenyl)methylene]ruthenium (CAS: 301224-40-8)?

This compound is used primarily in the pharmaceutical industry for its catalytic properties in organic synthesis. It is also utilized in the polymer industry for its catalytic activity and in sensors for its unique spectroscopic signatures. Additionally, it has potential applications in the semiconductor industry due to its electronic properties.

What precautions should be taken when handling (1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene)-dichloro-[(2-isopropoxyphenyl)methylene]ruthenium (CAS: 301224-40-8)?

Handling this compound requires the use of personal protective equipment (PPE) such as gloves, goggles, and a lab coat. Work should be performed in a fume hood. In case of a spill, it should be cleaned up immediately with appropriate absorbent materials. Always refer to the Safety Data Sheet (SDS) for detailed information on handling and disposal.