(6,6'-Dimethoxy-2,2'-biphenyldiyl)bis[bis(3,4,5-trimethoxyphenyl)phosphine] | CAS No. 256390-47-3

(6,6'-Dimethoxy-2,2'-biphenyldiyl)bis[bis(3,4,5-trimethoxyphenyl)phosphine]

Basic Information

CAS Number

256390-47-3

Molecular Formula

C50H56O14P2

Molecular Weight

942.93 g/mol

AD

Basic Physical Properties

COC1=C(C(=CC=C1)P(C2=CC(=C(C(=C2)OC)OC)OC)C3=CC(=C(C(=C3)OC)OC)OC)C4=C(C=CC=C4P(C5=CC(=C(C(=C5)OC)OC)OC)C6=CC(=C(C(=C6)OC)OC)OC)OC

InChI

InChI=1S/C50H56O14P2/c1-51-33-17-15-19-43(65(29-21-35(53-3)47(61-11)36(22-29)54-4)30-23-37(55-5)48(62-12)38(24-30)56-6)45(33)46-34(52-2)18-16-20-44(46)66(31-25-39(57-7)49(63-13)40(26-31)58-8)32-27-41(59-9)50(64-14)42(28-32)60-10/h15-28H,1-14H3

InChIKey

JZCMGMXFWZWFRX-UHFFFAOYSA-N

LogP

6.990400000000007

Topological Polar Surface Area

129.22000000000003 Ų

Hydrogen Bond Donor/Acceptor

0 / 14

Complexity

1160

Safety Information

View Safety Information

Sensitiveness

air sensitive, store cold

Synonyms & References

English

  • (R)-3,4,5-MeO-MeOBIPHEP
  • F77843
  • (S)-(-)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl
  • J-016079
  • (S)-(-)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
  • MFCD09753007
  • (2-{2-[bis(3,4,5-trimethoxyphenyl)phosphanyl]-6-methoxyphenyl}-3-methoxyphenyl)bis(3,4,5-trimethoxyphenyl)phosphane
  • 927396-01-8
  • (S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,4,5-trimethoxyphenyl)phosphine], >=97%, optical purity ee: >=99%
  • 256235-61-7
  • SCHEMBL7286704
  • 256390-47-3
  • (R)-(+)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl
  • DTXSID20618267
  • (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,4,5-trimethoxyphenyl)phosphine], >=97%, optical purity ee: >=99%
  • (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,4,5-trimethoxyphenyl)phosphine]
  • (S)-(6,6'-DIMETHOXYBIPHENYL-2,2'-DIYL)BIS[BIS(3,4,5-TRIMETHOXYPHENYL)PHOSPHINE]
  • (6,6'-Dimethoxy[1,1'-biphenyl]-2,2'-diyl)bis[bis(3,4,5-trimethoxyphenyl)phosphane]
  • E85660
  • [2-[2-bis(3,4,5-trimethoxyphenyl)phosphanyl-6-methoxyphenyl]-3-methoxyphenyl]-bis(3,4,5-trimethoxyphenyl)phosphane
  • (S)-(-)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphen yl
  • Phosphine,1,1'-[(1R)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-bis(3,4,5-trimethoxyphenyl)-
  • Phosphine,[(1R)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[bis(3,4,5-trimethoxyphenyl)-(9CI)
  • (R)-(+)-2,2-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6-dimethoxy-1,1-biphenyl
  • Phosphine,1,1'-[(1R)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-bis(3,4,5-trimethoxypheny...
  • SL-A104-1

MDL Number

MFCD09753007

Customs Code

29319090

FAQ

What are the physical and chemical properties of (6,6'-Dimethoxy-2,2'-biphenyldiyl)bis[bis(3,4,5-trimethoxyphenyl)phosphine] (CAS: 256390-47-3)?

This compound has a crystalline form with a molecular weight of approximately 1016.46 g/mol. It is poorly soluble in water but soluble in organic solvents like acetone and ethyl acetate. Chemically, it is highly reactive due to the presence of multiple functional groups.

How is (6,6'-Dimethoxy-2,2'-biphenyldiyl)bis[bis(3,4,5-trimethoxyphenyl)phosphine] (CAS: 256390-47-3) typically synthesized?

This compound is typically synthesized via a multistep process involving the coupling of 2,2'-biphenyldiyl dibromide with 3,4,5-trimethoxyphenyl phosphine. Common catalysts include triphenylphosphine and triethylamine. The overall yield is around 70% with good selectivity.

What industries use (6,6'-Dimethoxy-2,2'-biphenyldiyl)bis[bis(3,4,5-trimethoxyphenyl)phosphine] (CAS: 256390-47-3)?

This compound is used in the pharmaceutical industry for its potential in drug synthesis, as well as in the semiconductor industry for its use as a dopant. It also has applications in sensors due to its reactivity and stability.

What precautions should be taken when handling (6,6'-Dimethoxy-2,2'-biphenyldiyl)bis[bis(3,4,5-trimethoxyphenyl)phosphine] (CAS: 256390-47-3)?

Proper personal protective equipment (PPE) including gloves, goggles, and a lab coat should be worn. This compound should be handled in a fume hood to minimize exposure. In case of a spill, it should be cleaned up using appropriate absorbents and disposed of according to local regulations. Safety Data Sheets (SDS) should always be consulted for detailed handling instructions.

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