5,10,15,20-Tetrakis(4-nitrophenyl)porphyrin

Basic Information

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CAS Number

22843-73-8

Molecular Formula

C44H26N8O8

Molecular Weight

794.7 g/mol

Chemical Classification

Basic Chemical Raw Materials Organic Chemicals Carboxylic Acids

Basic Chemical Raw Materials Organic Chemicals Heterocyclic Compounds

Pharmaceutical Chemicals Pharmaceutical Intermediates Heterocyclic Intermediates

Fine Chemicals Dyes and Pigments Organic Dyes

Fine Chemicals Surfactants Anionic Surfactants

Laboratory Chemicals Research Chemicals Biochemical Reagents

Basic Physical Properties

Density

1.478

Refractive Index

1.732

SMILES

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C1=CC(=CC=C1C2=C3C=CC(=C(C4=NC(=C(C5=CC=C(N5)C(=C6C=CC2=N6)C7=CC=C(C=C7)[N+](=O)[O-])C8=CC=C(C=C8)[N+](=O)[O-])C=C4)C9=CC=C(C=C9)[N+](=O)[O-])N3)[N+](=O)[O-]

InChI

InChI=1S/C44H26N8O8/c53-49(54)29-9-1-25(2-10-29)41-33-17-19-35(45-33)42(26-3-11-30(12-4-26)50(55)56)37-21-23-39(47-37)44(28-7-15-32(16-8-28)52(59)60)40-24-22-38(48-40)43(36-20-18-34(41)46-36)27-5-13-31(14-6-27)51(57)58/h1-24,45,48H

InChIKey

FVHZCBQLLFLQAG-UHFFFAOYSA-N

Complexity

1300

Synonyms & References

English

YSSJ00494
5,10,15,20-tetrakis(4-nitrophenyl)-21,22-dihydroporphyrin
doi:10.14272/FVHZCBQLLFLQAG-LWQDQPMZSA-N.1
BS-49643
10.14272/FVHZCBQLLFLQAG-LWQDQPMZSA-N.1
5,10,15,20-Tetra(4-nitrophenyl)porphyrin
5,10,15,20-tetrakis(4-nitrophenyl)-21,23-dihydroporphyrin
tetrakis(p-nitrophenyl)porphyrin
21H,23H-Porphine, 5,10,15,20-tetrakis(4-nitrophenyl)-
5, 10, 15, 20-tetrakis(4-nitrophenyl)-21, 23-dihydroporphyrin
SCHEMBL11327076
Tetra(p-nitrophenyl)porphyrin
AKOS025394552
CS-0090578
22843-73-8
WLZ3228
AKOS005463574
5,10,15,20-tetrakis(4-nitrophenyl)porphyrin
5,10,15,20-(tetra-4-nitrophenyl)porphyrin
5,10,15,20-Tetrakis(4-nitrophenyl)porphyrin
21H,23H-Porphine,5,10,15,20-tetrakis(4-nitrophenyl)-
AGN-PC-00J5U6
ANW-65295
CTK8C0800
MolPort-000-742-847
STK530892
Tetra(4-nitrophenyl)porphyrin

MDL Number

MFCD01548089

FAQ

What are the physical and chemical properties of 5,10,15,20-Tetrakis(4-nitrophenyl)porphyrin (CAS: 22843-73-8)?

5,10,15,20-Tetrakis(4-nitrophenyl)porphyrin (CAS: 22843-73-8) is a solid, crystalline compound with a molecular weight of approximately 788.12 g/mol. It is poorly soluble in water but soluble in organic solvents such as chloroform. This compound has strong absorption in the visible region, making it useful for spectroscopic studies. It exhibits relatively high reactivity towards electron acceptors and can participate in various redox reactions.

How is 5,10,15,20-Tetrakis(4-nitrophenyl)porphyrin (CAS: 22843-73-8) typically synthesized?

5,10,15,20-Tetrakis(4-nitrophenyl)porphyrin is synthesized through the condensation of 4-nitrophenyl chloroperoxidase with meso-tetraphenylporphyrin. The reaction involves the substitution of each phenyl group of the porphyrin with 4-nitrophenyl groups. This process typically requires a molar excess of 4-nitrophenyl chloroperoxidase and is conducted in non-aqueous solvents to enhance the reaction selectivity and yield.

What industries use 5,10,15,20-Tetrakis(4-nitrophenyl)porphyrin (CAS: 22843-73-8)?

5,10,15,20-Tetrakis(4-nitrophenyl)porphyrin (CAS: 22843-73-8) is used in various industries. It is particularly valuable in the pharmaceutical industry for its application in photochemistry and photodynamic therapy. In the semiconductor industry, it serves as a dopant for certain materials. Additionally, it is used in chemical sensors due to its high sensitivity and selectivity towards various analytes.

What precautions should be taken when handling 5,10,15,20-Tetrakis(4-nitrophenyl)porphyrin (CAS: 22843-73-8)?

When handling 5,10,15,20-Tetrakis(4-nitrophenyl)porphyrin (CAS: 22843-73-8), it is important to wear appropriate personal protective equipment (PPE) such as gloves, safety goggles, and a lab coat. Work should be conducted in a fume hood to minimize inhalation risks. Spills should be cleaned up using appropriate absorbent materials, and the area should be well-ventilated. Always refer to the safety data sheet (SDS) for detailed handling and disposal information.