Phosphinous chloride, P,P-bis(tricyclo[3.3.1.13,7]dec-1-yl)- | CAS No. 157282-19-4

Phosphinous chloride, P,P-bis(tricyclo[3.3.1.13,7]dec-1-yl)-

Basic Information

CAS Number

157282-19-4

Molecular Formula

C20H30ClP

Molecular Weight

336.88 g/mol

AD

Basic Physical Properties

Solubility

Insuluble (2.2E-5 g/L) (25 ºC),

ClP(C12CC3CC(C2)CC(C1)C3)C12CC3CC(C2)CC(C1)C3

InChI

InChI=1S/C20H30ClP/c21-22(19-7-13-1-14(8-19)3-15(2-13)9-19)20-10-16-4-17(11-20)6-18(5-16)12-20/h13-18H,1-12H2

InChIKey

BVOJCPQWSXCCKU-UHFFFAOYSA-N

LogP

6.559700000000006

Topological Polar Surface Area

0.0 Ų

Hydrogen Bond Donor/Acceptor

0 / 0

Safety Information

View Safety Information

Sensitiveness

moisture sensitive

Synonyms & References

English

  • Di(adamantan-1-yl)chlorophosphine
  • di-1-adamantylchlorophosphine
  • Di(1-adaMantyl)chlorophosphine
  • Bis(1-adamantyl)phosphinous chloride
  • Diadamantylchlorophosphine
  • Bis(1-AdaMantyl)Chlorophosphine
  • Bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphinous chloride

MDL Number

MFCD18910707

FAQ

What are the physical and chemical properties of Phosphinous chloride, P,P-bis(tricyclo[3.3.1.13,7]dec-1-yl) (CAS: 157282-19-4)?

Phosphinous chloride, P,P-bis(tricyclo[3.3.1.13,7]dec-1-yl) (CAS: 157282-19-4) is a crystalline solid with a molecular weight of approximately 294.3 g/mol. It has a low solubility in water but is soluble in organic solvents. The compound is less reactive compared to simpler phosphorus compounds but can undergo nucleophilic substitution reactions. It is stable under normal conditions but should be handled with care due to its potential for decomposition upon heating or exposure to light.

How is Phosphinous chloride, P,P-bis(tricyclo[3.3.1.13,7]dec-1-yl) (CAS: 157282-19-4) typically synthesized?

Phosphinous chloride, P,P-bis(tricyclo[3.3.1.13,7]dec-1-yl) (CAS: 157282-19-4) can be synthesized by reacting tricyclo[3.3.1.13,7]dec-1-yl phosphite with phosphorus oxychloride. The reaction typically requires a mild catalyst and is carried out under anhydrous conditions to improve yield. The use of a fume hood is recommended to mitigate the generation of toxic fumes during the synthesis process.

What industries use Phosphinous chloride, P,P-bis(tricyclo[3.3.1.13,7]dec-1-yl) (CAS: 157282-19-4)?

Phosphinous chloride, P,P-bis(tricyclo[3.3.1.13,7]dec-1-yl) (CAS: 157282-19-4) finds applications in the pharmaceutical industry for the synthesis of certain drugs, as well as in the polymer industry for improving material properties. It is also used in the production of sensors and semiconductors due to its unique chemical and physical properties.

What precautions should be taken when handling Phosphinous chloride, P,P-bis(tricyclo[3.3.1.13,7]dec-1-yl) (CAS: 157282-19-4)?

When handling Phosphinous chloride, P,P-bis(tricyclo[3.3.1.13,7]dec-1-yl) (CAS: 157282-19-4), it is essential to use appropriate personal protective equipment (PPE) such as gloves, goggles, and a lab coat. Work should be conducted in a well-ventilated area or fume hood. Spills should be handled with caution using appropriate absorbent materials and the incident should be reported to the safety department. A Material Safety Data Sheet (MSDS) should be consulted for specific safety guidelines and emergency procedures.

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