Diphenyliodonium chloride

Basic Information

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CAS Number

1483-72-3

Molecular Formula

C12H10ClI

Molecular Weight

316.56 g/mol

Chemical Classification

Agricultural Chemicals Pesticides Herbicides

Basic Physical Properties

Melting Point

233-235 °C (subl.)

Boiling Point

°Cat760mmHg

Water Solubility

Soluble in water and methanol.

SMILES

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C1=CC=C(C=C1)[I+]C2=CC=CC=C2.[Cl-]

InChI

InChI=1S/C12H10I.ClH/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;1H/q+1;/p-1

InChIKey

RSJLWBUYLGJOBD-UHFFFAOYSA-M

LogP

-3.18100

Complexity

116

Safety Information

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Hazard Statement

H301 Toxic if swallowed
Acute toxicity, oral

H315 Causes skin irritation
Skin corrosion/irritation

H319 Causes serious eye irritation
Serious eye damage/eye irritation

Hazard Class

Class 6.1 Class 6.1

Sensitiveness

Light Sensitive

Synonyms & References

English

Iodonium, diphenyl-, chloride(1:1)
SY061904
D2356
EINECS 216-049-8
diphenyliodanium;chloride
CS-W012024
AKOS015833159
FT-0625259
NS00081204
Diphenyl iodonium chloride
AI3-17092
MFCD00011909
s11853
Diphenyliodonium chloride
Dibenziodolium, chloride (1:1)
FT-0625258
Iodonium, diphenyl-, chloride
RSJLWBUYLGJOBD-UHFFFAOYSA-M
Iodonium, diphenyl-, chloride (1:1)
NSC 134275
SCHEMBL15641
diphenyliodanium chloride
J-008463
1483-72-3
FT-0625265
DTXSID60883679
CHEMBL481680
DS-14154
chlorodiphenyliodonium
diphenyl-iodoniuchloride
Diphenyliodonium

MDL Number

MFCD00011909

Customs Code

2903999090

FAQ

What are the physical and chemical properties of Diphenyliodonium chloride (CAS: 1483-72-3)?

Diphenyliodonium chloride is a crystalline compound with a molecular weight of 286.17 g/mol. It has a low solubility in water but is more soluble in organic solvents like dichloromethane. Chemically, it is a strong oxidizing agent and can react with reducing agents. It is stable under normal conditions but should be handled with care due to its reactivity.

How is Diphenyliodonium chloride (CAS: 1483-72-3) typically synthesized?

Diphenyliodonium chloride is typically synthesized by the reaction of phenyllithium with iodine in an inert solvent such as THF. The process involves the formation of phenyl iodide, which then reacts with another equivalent of phenyllithium to form the diphenyliodonium ion. This ion then reacts with chloride to give the final product. The yield is generally high, and the reaction is carried out under anhydrous conditions.

What industries use Diphenyliodonium chloride (CAS: 1483-72-3)?

Diphenyliodonium chloride is used in the pharmaceutical industry for the synthesis of certain drugs, in the polymer industry for the modification of polymers, and in the semiconductor industry for etching processes. It is also utilized in the production of sensors and in organic chemistry for various transformations.

What precautions should be taken when handling Diphenyliodonium chloride (CAS: 1483-72-3)?

When handling Diphenyliodonium chloride, it is essential to wear appropriate personal protective equipment (PPE) such as gloves, goggles, and a lab coat. The compound should be handled in a fume hood due to its reactivity. Spills should be cleaned up immediately using appropriate absorbent materials. A safety data sheet (SDS) should be consulted for detailed handling and disposal instructions.