(R,R)-(-)-N,N'-Bis(3,5-di-tertbutylsalicylidene)-1,2- cyclohexanediaminomanganese(III) chloride | CAS No. 138124-32-0
(R,R)-(-)-N,N'-Bis(3,5-di-tertbutylsalicylidene)-1,2- cyclohexanediaminomanganese(III) chloride
Basic Information
CAS Number
138124-32-0
Molecular Formula
C36H52ClMnN2O2
Molecular Weight
635.2 g/mol
AD
Basic Physical Properties
Melting Point
326°C
Specific Rotation
D23 +580° (c = 0.01 in ethanol)
Safety Information
View Safety InformationHazard Statement
H315
Causes skin irritation
Skin corrosion/irritation
Skin corrosion/irritation
H319
Causes serious eye irritation
Serious eye damage/eye irritation
Serious eye damage/eye irritation
Synonyms & References
English
- 138124-32-0
- 45S483EOVD
- Jacobsen's catalyst(R,R)
- (1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butyl-salicylidene)]Mn(III) chloride
- MANGANESE, CHLORO((REL-2,2'-((1R,2R)-1,2-CYCLOHEXANEDIYLBIS((NITRILO-.KAPPA.N)METHYLIDYNE))BIS(4,6-BIS(1,1-DIMETHYLETHYL)PHENOLATO-.KAPPA.O))(2-))-, (SP-5-13)-
- (R,R)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) Chloride
- UNII-45S483EOVD
- WPP775Y8PO
- LJVAWOSDJSQANR-SEILFYAJSA-K
- Manganese, chloro((rel-2,2'-((1R,2R)-1,2-cyclohexanediylbis((nitrilo-kappaN)methylidyne))bis(4,6-bis(1,1-dimethylethyl)phenolato-kappaO))(2-))-, (sp-5-13)-
- (N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine)manganese(III) chloride, (R,R)-
- UNII-WPP775Y8PO
- MANGANESE, CHLORO((2,2'-((1R,2R)-1,2-CYCLOHEXANEDIYLBIS((NITRILO-.KAPPA.N)METHYLIDYNE))BIS(4,6-BIS(1,1-DIMETHYLETHYL)PHENOLATO-.KAPPA.O))(2-))-, (SP-5-13)-
- Manganese, chloro((2,2'-((1R,2R)-1,2-cyclohexanediylbis((nitrilo-kappaN)methylidyne))bis(4,6-bis(1,1-dimethylethyl)phenolato-kappaO))(2-))-, (sp-5-13)-
- AKOS037647740
- Jacobsen's catalyst [MI]
- DTXSID901028812
- 2,4-ditert-butyl-6-[[(1R,2R)-2-[(3,5-ditert-butyl-2-oxidophenyl)methylideneamino]cyclohexyl]iminomethyl]phenolate;manganese(3+);chloride
- (N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine)manganese(III) chloride, (R,R)-rel-
- (N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine)manganese(III) chloride, (RS,RS)-
- (-)-Chloro((1R,2R)-4,4',6,6'-tetra-tert-butyl-2,2'-(cyclohexane-1,2-diylbis(nitrilomethylidyne))diphenolato(manganese(III)
- 149656-63-3
- (R,R)-Jacobsen's catalyst
- MFCD02101664
- Jacobsen's catalyst (R,R)-form [MI]
- Manganese, chloro((2,2'-(1,2-cyclohexanediylbis(nitrilomethylidyne))bis(4,6-bis(1,1-dimethylethyl)phenolato))(2-)-N,N',O,O')-, (sp-5-13-(trans))-
- (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
- (R,R)-(N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine)manganese(III) chloride
- Jacobsen's catalyst
- GEO-03071
- AS-74616
MDL Number
MFCD02101664
Customs Code
29349990
FAQ
What are the physical and chemical properties of (R,R)-(-)-N,N'-Bis(3,5-di-tertbutylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride (CAS: 138124-32-0)?
The compound is a crystalline solid with a high molecular weight. It has limited solubility in water and organic solvents. Chemically, it is a manganese(III) complex with a high reactivity towards reducing agents. It exhibits stability in air and is less prone to hydrolysis.
How is (R,R)-(-)-N,N'-Bis(3,5-di-tertbutylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride (CAS: 138124-32-0) typically synthesized?
This compound is typically synthesized by reacting a mixture of 3,5-di-tertbutylsalicylaldehyde and 1,2-cyclohexanediamine with manganese(III) chloride in an appropriate solvent under controlled conditions. The reaction involves the formation of a complex through coordination of the ligands to manganese(III) ions.
What industries use (R,R)-(-)-N,N'-Bis(3,5-di-tertbutylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride (CAS: 138124-32-0)?
This compound is used in the pharmaceutical industry for its antioxidant and anti-inflammatory properties. It is also utilized in the polymer industry to enhance thermal stability and in the production of advanced materials. Additionally, it has applications in sensors for detecting specific chemical species.
What precautions should be taken when handling (R,R)-(-)-N,N'-Bis(3,5-di-tertbutylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride (CAS: 138124-32-0)?
Proper personal protective equipment (PPE) such as gloves and safety goggles should be worn. Handling should be done in a fume hood to minimize exposure. Spills should be cleaned up using appropriate absorbent materials and disposed of according to local regulations. Always consult the Safety Data Sheet (SDS) for detailed handling and storage instructions.
Related Compounds
![N-(2-Methoxyphenyl)-N-[(4-methylphenyl)sulfonyl]-beta-alanine structure](https://static.chemtradehub.com/structs/103/103687-96-3-8086.webp "N-(2-Methoxyphenyl)-N-[(4-methylphenyl)sulfonyl]-beta-alanine structure")
N-(2-Methoxyphenyl)-N-[(4-methylphenyl)sulfonyl]-beta-alanine
CAS Number:
103687-96-3
Molecular Formula:
C17H19NO5S
![5'-O-[Bis(4-methoxyphenyl)(phenyl)methyl]cytidine structure](https://static.chemtradehub.com/structs/112/112897-99-1-d1f4.webp "5'-O-[Bis(4-methoxyphenyl)(phenyl)methyl]cytidine structure")
5'-O-[Bis(4-methoxyphenyl)(phenyl)methyl]cytidine
CAS Number:
112897-99-1
Molecular Formula:
C30H31N3O7
![(3S,4R)-3-Hydroxy-2,2-dimethyl-4-[(3-oxo-1-cyclopenten-1-yl)oxy]-6-chromanecarbonitrile structure](https://static.chemtradehub.com/structs/121/121055-10-5-583d.webp "(3S,4R)-3-Hydroxy-2,2-dimethyl-4-[(3-oxo-1-cyclopenten-1-yl)oxy]-6-chromanecarbonitrile structure")
(3S,4R)-3-Hydroxy-2,2-dimethyl-4-[(3-oxo-1-cyclopenten-1-yl)oxy]-6-chromanecarbonitrile
CAS Number:
121055-10-5
Molecular Formula:
C17H17NO4
![Methyl 5-chloropyrazolo[1,5-a]pyrimidine-2-carboxylate structure](https://static.chemtradehub.com/structs/126/1263059-26-2-d6da.webp "Methyl 5-chloropyrazolo[1,5-a]pyrimidine-2-carboxylate structure")
Methyl 5-chloropyrazolo[1,5-a]pyrimidine-2-carboxylate
CAS Number:
1263059-26-2
Molecular Formula:
C8H6ClN3O2
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