Advanced engineering strategies for Li2S cathodes in lithium–sulfur batteries

Literature Information

Publication Date 2023-11-22
DOI 10.1039/D3TA06057H
Impact Factor 12.732
Authors

Guowei Gao, Xiaochen Yang, Jingxuan Bi, Wanqing Guan, Zhuzhu Du


View Original

Abstract

In the rapidly advancing landscape of portable electronic devices, lithium–sulfur batteries (LSBs) have risen to prominence as a viable successor to traditional lithium-ion batteries. This review delves into the potential of Li2S, showcasing it as an exemplary cathode with high energy density, safety, and efficiency for LSBs. However, these promising facets are shadowed by notable impediments to its practical deployment, including constraints like inadequate electronic and ionic conductivity, an elevated initial activation overpotential, and the vexing challenge posed by the shuttle effect. The review systematically explores various strategies for overcoming these hindrances, with a concentrated focus on the engineering of Li2S, host materials and additives. While existing literature has addressed Li2S cathode technology to some extent, this review goes a step further by meticulously examining neglected aspects like polycrystalline Li2S and artificial cathode electrolyte interfaces. Through a deep analysis of the redox process of the Li2S cathode and by integrating diverse engineering strategies into three coherent areas, the review serves as a comprehensive guide that illuminates new insights and charts future pathways in the pursuit of high-performance LSBs utilizing Li2S cathode materials.

Related Literature

Ru(ii)-cornered coordination cage that senses guest inclusion by color change

Ken-ichi Yamashita, Masaki Kawano, Makoto Fujita

2007-09-24 Communication

DOI: 10.1039/B712529A

An organocatalytic approach to the core of eunicellin

Ryan Gilmour, Timothy J. Prior

2007-08-20 Communication

DOI: 10.1039/B709322E

Tandem pinacol coupling–rearrangement of aromatic aldehydes with hydrogen catalyzed by a combination of a platinum complex and a polyoxometalate

Olena Branytska, Linda J. W. Shimon, Ronny Neumann

2007-08-20 Communication

DOI: 10.1039/B710100G

Assembly of a planar, tricyclic B4N8 framework with s-indacene structure

Hanh V. Ly, Heikki M. Tuononen, Masood Parvez, Roland Roesler

2007-09-06 Communication

DOI: 10.1039/B709270A

Sol–gel encapsulation of cells is not limited to silica: long-term viability of bacteria in alumina matrices

Makhlouf Amoura, Nadine Nassif, Cécile Roux, Jacques Livage, Thibaud Coradin

2007-09-07 Communication

DOI: 10.1039/B711380C

Electrochemical STM observation of new structures of CO adsorbed on a Pt(111) electrode surface

Changhoon Jung, Bonseong Ku, Jandee Kim, Choong Kyun Rhee

2006-04-21 Communication

DOI: 10.1039/B603033E

Evaluation of a carbohydrate–π interaction in a peptide model system

Sarah E. Kiehna, Zachary R. Laughrey, Marcey L. Waters

2007-08-28 Communication

DOI: 10.1039/B711431A

Symmetry and optical spectra: a “silent” 1 : 2 Np(v)–oxydiacetate complex

Guoxin Tian, Linfeng Rao, Allen Oliver

2007-08-06 Communication

DOI: 10.1039/B706825E

You might also like

Compound Q&A

How should waste containing 2-Ethyl-4-Methyl-1H-Imidazole-5-Carbaldehyde (CAS: 88634-80-4) be handled?

Waste containing 2-Ethyl-4-Methyl-1H-Imidazole-5-Carbaldehyde (CAS: 88634-80-4) ...

88634-80-42-Ethyl-4-Methyl-1H-...
Compound Q&A

What industries use Triethoxy(octyl)silane (CAS: 1385031-14-0)?

Triethoxy(octyl)silane (CAS: 1385031-14-0) is widely used in the pharmaceuticals...

1385031-14-0Triethoxy(octyl)sila...
Compound Q&A

Are there alternatives to 3-iodo-7-nitro-1H-indazole (CAS: 864724-64-1) in synthesis?

Several alternatives to 3-iodo-7-nitro-1H-indazole (CAS: 864724-64-1) exist in t...

864724-64-13-iodo-7-nitro-1H-in...
Compound Q&A

Are there alternatives to Benzene, bis[(trimethoxysilyl)ethyl] (CAS: 266317-71-9) in synthesis?

Yes, there are alternatives to Benzene, bis[(trimethoxysilyl)ethyl] (CAS: 266317...

266317-71-9Benzene, bis[(trimet...
Compound Q&A

Is Isothiazole-3-carbonitrile (CAS: 1452-17-1) safe?

Isothiazole-3-carbonitrile (CAS: 1452-17-1) is generally considered safe when us...

1452-17-1Isothiazole-3-carbon...
Compound Q&A

Is (3-Chlorophenyl)methanol (CAS: 873-63-2) safe?

(3-Chlorophenyl)methanol (CAS: 873-63-2) is considered low to moderately toxic. ...

873-63-2(3-Chlorophenyl)meth...
Compound Q&A

How is (2S,3S)-2-Hydroxy-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-3-(2-naphthyl)propanoic acid (CAS: 959583-98-3) typically synthesized?

(2S,3S)-2-Hydroxy-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-3-(2-naphthyl)pr...

959583-98-3(2S,3S)-2-Hydroxy-3-...
Compound Q&A

What precautions should be taken when handling Methyl 2-(bromomethyl)-5-methoxybenzoate (CAS: 788081-99-2)?

Proper handling of methyl 2-(bromomethyl)-5-methoxybenzoate requires the use of ...

788081-99-2Methyl 2-(bromomethy...
Compound Q&A

What is 6,8-Dibromoimidazo[1,2-a]pyridine-2-carboxylic acid (CAS: 904805-36-3)?

6,8-Dibromoimidazo[1,2-a]pyridine-2-carboxylic acid (CAS: 904805-36-3) is an aro...

904805-36-36,8-Dibromoimidazo[1...
Compound Q&A

Is 3-Amino-5-bromo-2-pyridinecarbonitrile (CAS: 573675-27-1) safe?

3-Amino-5-bromo-2-pyridinecarbonitrile is considered safe when handled under pro...

573675-27-13-Amino-5-bromo-2-py...

Source Journal

Journal of Materials Chemistry A

Journal of Materials Chemistry A
CiteScore: 19.5
Self-citation Rate: 4.7%
Articles per Year: 2211

Journal of Materials Chemistry A, B & C cover high quality studies across all fields of materials chemistry. The journals focus on those theoretical or experimental studies that report new understanding, applications, properties and synthesis of materials. The journals have a strong history of publishing quality reports of interest to interdisciplinary communities and providing an efficient and rigorous service through peer review and publication. The journals are led by an international team of Editors-in-Chief and Associate Editors who are all active researchers in their fields. Journal of Materials Chemistry A, B & C are separated by the intended application of the material studied. Broadly, applications in energy and sustainability are of interest to Journal of Materials Chemistry A, applications in biology and medicine are of interest to Journal of Materials Chemistry B, and applications in optical, magnetic and electronic devices are of interest to Journal of Materials Chemistry C. More than one Journal of Materials Chemistry journal may be suitable for certain fields and researchers are encouraged to submit their paper to the journal that they feel best fits for their particular article. Example topic areas within the scope of Journal of Materials Chemistry A are listed below. This list is neither exhaustive nor exclusive. Artificial photosynthesis Batteries Carbon dioxide conversion Catalysis Fuel cells Gas capture/separation/storage Green/sustainable materials Hydrogen generation Hydrogen storage Photocatalysis Photovoltaics Self-cleaning materials Self-healing materials Sensors Supercapacitors Thermoelectrics Water splitting Water treatment

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.