Gyroscope-like molecules consisting of three-spoke stators that enclose “switchable” neutral dipolar rhodium rotators; reversible cycling between faster and slower rotating Rh(CO)I and Rh(CO)2I species
Literature Information
Leyong Wang, Takanori Shima, Frank Hampel, J. A. Gladysz
trans-Rh(CO)(Cl)(P((CH2)14)3P) is prepared from trans-Rh(CO)(Cl)(P((CH2)6CHCH2)3)2 by a metathesis/hydrogenation sequence, and converted by substitution or addition reactions to Rh(CO)(I), Rh(CO)2(I), Rh(CO)(NCS), and Rh(CO)(Cl)(Br)(CCl3) species; the Rh(CO)(Cl) and Rh(CO)(I) moieties rapidly rotate within the cage-like diphosphine, but the other rhodium moieties do not.
Recommended Journals

Photochemical & Photobiological Sciences

Advanced Engineering Materials

Coloration Technology

Foundations of Chemistry

Environmental Toxicology and Pharmacology

Current Pharmaceutical Biotechnology

European Journal of Organic Chemistry

Contact Lens & Anterior Eye

Lab on a Chip

Angewandte Chemie International Edition
Related Literature
Density functional theoretical (DFT) and surface-enhanced Raman spectroscopic study of guanine and its alkylated derivatives Part 2: Surface-enhanced Raman scattering on silver surfaces
Bernd Giese, Don McNaughton
DOI: 10.1039/B203830G
A quasiclassical trajectory and quantum mechanical study of the O(1D) + D2 reaction dynamics. Comparison with high resolution molecular beam experiments
V. J. Herrero, B. Martínez-Haya
DOI: 10.1039/B203755F
Simulation of maintenance of the epidermis
Bengt Kasemo
DOI: 10.1039/B205795F
Mechanical response of some peculiar superionic glasses at ultrasonic frequencies
Maria Cutroni, Andrea Mandanici, Ezio Bruno
DOI: 10.1039/B203311A
Constructing a map from the electron density to the exchange–correlation potential
Aron J. Cohen, Nicholas C. Handy
DOI: 10.1039/B205854E
Gallium(iii) hydration in aqueous solution of perchlorate, nitrate and sulfate. Raman and 71-Ga NMR spectroscopic studies and ab initio molecular orbital calculations of gallium(iii) water clusters
Wolfram W. Rudolph, Cory C. Pye
DOI: 10.1039/B202567C
High-temperature transformations of organised mesoporous alumina
Jiří Čejka, Patricia J. Kooyman, Lenka Veselá, Jiří Rathouský, Arnošt Zukal
DOI: 10.1039/B205100A
A fully direct RI-HF algorithm: Implementation, optimised auxiliary basis sets, demonstration of accuracy and efficiency
DOI: 10.1039/B204199P
MSA-NRTL model for the description of the thermodynamic properties of electrolyte solutions
J.-P. Simonin, O. Bernard, W. Kunz
DOI: 10.1039/B204841H
You might also like
How should waste containing 2-Ethyl-4-Methyl-1H-Imidazole-5-Carbaldehyde (CAS: 88634-80-4) be handled?
Waste containing 2-Ethyl-4-Methyl-1H-Imidazole-5-Carbaldehyde (CAS: 88634-80-4) ...
What industries use Triethoxy(octyl)silane (CAS: 1385031-14-0)?
Triethoxy(octyl)silane (CAS: 1385031-14-0) is widely used in the pharmaceuticals...
Are there alternatives to 3-iodo-7-nitro-1H-indazole (CAS: 864724-64-1) in synthesis?
Several alternatives to 3-iodo-7-nitro-1H-indazole (CAS: 864724-64-1) exist in t...
Are there alternatives to Benzene, bis[(trimethoxysilyl)ethyl] (CAS: 266317-71-9) in synthesis?
Yes, there are alternatives to Benzene, bis[(trimethoxysilyl)ethyl] (CAS: 266317...
Is Isothiazole-3-carbonitrile (CAS: 1452-17-1) safe?
Isothiazole-3-carbonitrile (CAS: 1452-17-1) is generally considered safe when us...
Is (3-Chlorophenyl)methanol (CAS: 873-63-2) safe?
(3-Chlorophenyl)methanol (CAS: 873-63-2) is considered low to moderately toxic. ...
How is (2S,3S)-2-Hydroxy-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-3-(2-naphthyl)propanoic acid (CAS: 959583-98-3) typically synthesized?
(2S,3S)-2-Hydroxy-3-({[(2-methyl-2-propanyl)oxy]carbonyl}amino)-3-(2-naphthyl)pr...
What precautions should be taken when handling Methyl 2-(bromomethyl)-5-methoxybenzoate (CAS: 788081-99-2)?
Proper handling of methyl 2-(bromomethyl)-5-methoxybenzoate requires the use of ...
What is 6,8-Dibromoimidazo[1,2-a]pyridine-2-carboxylic acid (CAS: 904805-36-3)?
6,8-Dibromoimidazo[1,2-a]pyridine-2-carboxylic acid (CAS: 904805-36-3) is an aro...
Is 3-Amino-5-bromo-2-pyridinecarbonitrile (CAS: 573675-27-1) safe?
3-Amino-5-bromo-2-pyridinecarbonitrile is considered safe when handled under pro...
Source Journal
Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry




![L-Threonine, N-[[4,7,10-tris(carboxymethyl)-1,4,7,10-tetraazacyclododec-1-yl]acetyl]-D-phenylalanyl-L-cysteinyl-L-tyrosyl-D-tryptophyl-L-lysyl-L-threonyl-L-cysteinyl-, cyclic (2→7)-disulfide, acetate (salt) (9CI) structure L-Threonine, N-[[4,7,10-tris(carboxymethyl)-1,4,7,10-tetraazacyclododec-1-yl]acetyl]-D-phenylalanyl-L-cysteinyl-L-tyrosyl-D-tryptophyl-L-lysyl-L-threonyl-L-cysteinyl-, cyclic (2→7)-disulfide, acetate (salt) (9CI) structure](https://static.chemtradehub.com/structs/177/177943-89-4-6312.webp)