Symmetry and optical spectra: a “silent” 1 : 2 Np(v)–oxydiacetate complex

Literature Information

Publication Date 2007-08-06
DOI 10.1039/B706825E
Impact Factor 6.222
Authors

Guoxin Tian, Linfeng Rao, Allen Oliver


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Abstract

The 1 : 2 Np(V)–oxydiacetate complex, NpO2(ODA)23−, identified by single-crystal X-ray diffractometry for the first time, is centrosymmetric around the Np atom so that the f–f transitions of Np(V) are forbidden, resulting in the “silence” of the absorption and diffuse reflectance spectra of this complex in solution and the solid state in the near-IR and visible regions.

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