Side-chain meta[6]cycloparaphenylene-based nanoring-containing polymers
Literature Information
Jiale Zhang, He Cheng, Zihao Meng, Hao Zhang, Zhenyang Luo, Mohd. Muddassir, Xiang Li, Ye Sha
We report the first controlled polymerization of the norbornene-functionalized meta[6]cycloparaphenylene (m[6]CPP) monomer through ring-opening metathesis polymerization (ROMP). The m[6]CPP nanohoop is incorporated as a pendant motif away from the polymer backbone. The intrinsic unique photophysical properties of m[6]CPP are largely retained when it is converted into a polymer. This work represents a convergence of precise organic synthesis and macromolecular chemistry toward functional carbon-based materials.
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