Orthogonal polymerization of aziridine with cyclic carbonates for constructing amphiphilic block copolymers

Literature Information

Publication Date 2023-10-31
DOI 10.1039/D3PY01045G
Impact Factor 5.582
Authors

Xiao-Hui Guo, Ge-Ge Gu, Tian-Jun Yue, Wei-Min Ren


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Abstract

Herein, we describe a novel strategy for synthesizing amphiphilic block copolymers, comprising acidified polyamine and polycarbonate segments, by the orthogonal polymerization of aziridine and cyclic carbonates. Controlled experiments revealed that the cationic ring-opening polymerization (ROP) of aziridine and the anionic ROP of cyclic carbonates proceeded simultaneously to accomplish chain propagation.

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Polymer Chemistry

Polymer Chemistry
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