Hydrothermal conversion of cerium oxalate to CeO2: a parade of oxalate and water coordination modes
Literature Information
Navid Assi, Christophe Lahoud, Petr Brázda, Dominika Zákutná, Daniel N. Rainer, Jakub Hraníček, Jan Rohlíček, Václav Tyrpekl
Hydrothemal conversion of lanthanide/actinide oxalate salts to nanocrystalline oxide has gained technological importance in the chemistry of f-elements. Herein, we present a study describing the mechanism behind the hydrothermal recrystallization and decomposition of cerium (and Ce-Gd) oxalate to oxide. Structural determination of all intermediate nanocrystalline products was possible thanks to three-dimensional electron diffraction. This work reveals the enormous structural abilities of simple oxalate ligands.
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New Journal of Chemistry

NJC (New Journal of Chemistry) is a broad-based primary journal encompassing all branches of chemistry and its sub-disciplines. It contains full research articles, communications, perspectives and focus articles. This well-established journal, owned by the Centre National de la Recherche Scientifique (CNRS) of France, has been co-published with the Royal Society of Chemistry since January 1998. NJC is the forum for the publication of high-quality, original and significant work that opens new directions in chemistry or other scientific disciplines. In addition to having a significant chemical component, work published in NJC must demonstrate that it will have an impact on areas of research other than that of the reported work.











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