[RbSr3X][(BS3)2] (X = Cl, Br): two salt-inclusion thioborates with large birefringence and structure transformation from centrosymmetric to asymmetric

Literature Information

Publication Date 2023-11-18
DOI 10.1039/D3CC05205B
Impact Factor 6.222
Authors


View Original

Abstract

[RbSr3X][(BS3)2] (X = Cl, Br), two salt-inclusion chalcogenides with planar [BS3] as anionic units, were obtained. Structure analysis indicates that the size effect of halogens may adjust the arrangement between the [BS3] units and further lead to the CS-to-NCS structure transformation. Experimental characterizations reveal that they have wide bandgaps (3.64–3.70 eV), large birefringence (0.136–0.144) and high LIDT (12–14 × AgGaS2). This work indicates that the thioborate family is a rich source to explore structure chemistry and promising infrared functional materials.

Related Literature

Adsorption studies of a phosphonic acid on ITO: film coverage, purity, and induced electronic structure changes

S. A. Paniagua, E. L. Li, S. R. Marder

2013-12-19 Paper

DOI: 10.1039/C3CP54637C

Emission ellipsometry used to probe aggregation of the luminescent 2,1,3-benzothiadiazole dyes and ordering in an E7 liquid crystal matrix

Paulo Alliprandini Filho, Gustavo G. Dalkiranis, Raigna A. S. Z. Armond, Eralci M. Therézio, Ivan H. Bechtold, André A. Vieira, Rodrigo Cristiano, Hugo Gallardo, Osvaldo N. Oliveira, Jr.

2013-11-26 Paper

DOI: 10.1039/C3CP53803F

Self-aggregation mechanisms of N-alkyl derivatives of urea and thiourea

Monika Obrzud, Maria Rospenk, Aleksander Koll

2013-12-16 Paper

DOI: 10.1039/C3CP53582G

Chemical vs. electrochemical extraction of lithium from the Li-excess Li1.10Mn1.90O4 spinel followed by NMR and DRX techniques

S. Martinez, I. Sobrados, D. Tonti, J. M. Amarilla, J. Sanz

2014-01-13 Paper

DOI: 10.1039/C3CP54386B

Improving O2 production of WO3 photoanodes with IrO2 in acidic aqueous electrolyte

Joshua M. Spurgeon, Jesus M. Velazquez, Matthew T. McDowell

2014-01-10 Paper

DOI: 10.1039/C3CP55527E

The role of charge transfer in the energy level alignment at the pentacene/C60 interface

J. Beltrán, F. Flores, J. Ortega

2014-01-06 Paper

DOI: 10.1039/C3CP55004D

Promising electrochemical hydrogen storage properties of thick Mg–Pd films obtained by insertion of thin Ti interlayers

Gongbiao Xin, Yanyan Wang, He Fu, Jie Zheng, Xingguo Li

2013-12-09 Paper

DOI: 10.1039/C3CP54714K

You might also like

Compound Q&A

What is the market or research trend for N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0)?

N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0) is increasingly being used ...

52818-63-0N-(4-Methoxybenzyl)-...
Compound Q&A

What precautions should be taken when handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate (CAS: 1050507-06-6)?

When handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate, appropriate p...

1050507-06-6Ethyl 4-(2-chlorophe...
Compound Q&A

What regulatory guidelines apply to diethyldiselane (CAS: 628-39-7)?

Diethyldiselane (CAS: 628-39-7) is classified under the Globally Harmonized Syst...

628-39-7Diethyldiselane
Compound Q&A

What is the market or research trend for oxocopper (CAS: 12053-18-8)?

The market for oxocopper (CAS: 12053-18-8) is primarily driven by its use in cat...

12053-18-8oxocopper; oxo-(oxoc...
Compound Q&A

What is the market or research trend for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-carboxylic acid?

The market for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-c...

1268519-54-55-{[(2-Methyl-2-prop...
Compound Q&A

What is 2-(1-Pyrrolidinyl)-4-pyridinamine (CAS: 35981-63-6)?

2-(1-Pyrrolidinyl)-4-pyridinamine is a chemical compound with the CAS number 359...

35981-63-62-(1-Pyrrolidinyl)-4...
Compound Q&A

What are the physical and chemical properties of 2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1)?

2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1) is a crystalline sol...

91556-75-12-(3-Pyridinyl)-1-az...
Compound Q&A

How is (S)-Alpha-allyl-proline hydrochloride (CAS: 129704-91-2) typically synthesized?

(S)-Alpha-allyl-proline hydrochloride is usually synthesized via a Wittig reacti...

129704-91-2(S)-Alpha-allyl-prol...
Compound Q&A

What is 3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5)?

3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5) is an organic compound w...

4857-42-53-Methyl-1,2-oxazole...
Compound Q&A

How is Lys-SMCC-DM1 (CAS: 1281816-04-3) typically synthesized?

Lys-SMCC-DM1 is synthesized via a multi-step process involving the coupling of S...

1281816-04-3Lys-SMCC-DM1

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.