[RbSr3X][(BS3)2] (X = Cl, Br): two salt-inclusion thioborates with large birefringence and structure transformation from centrosymmetric to asymmetric

Literature Information

Publication Date 2023-11-18
DOI 10.1039/D3CC05205B
Impact Factor 6.222
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Abstract

[RbSr3X][(BS3)2] (X = Cl, Br), two salt-inclusion chalcogenides with planar [BS3] as anionic units, were obtained. Structure analysis indicates that the size effect of halogens may adjust the arrangement between the [BS3] units and further lead to the CS-to-NCS structure transformation. Experimental characterizations reveal that they have wide bandgaps (3.64–3.70 eV), large birefringence (0.136–0.144) and high LIDT (12–14 × AgGaS2). This work indicates that the thioborate family is a rich source to explore structure chemistry and promising infrared functional materials.

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