Hydrogenation of levulinic acid to γ-valerolactone over hydrophobic Ru@HCP catalysts

Literature Information

Publication Date 2023-11-13
DOI 10.1039/D3CC04405J
Impact Factor 6.222
Authors

Weiqiang Yu, Xinhong Wang, Song Shi


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Abstract

This study introduces an efficient strategy for promoting the synthesis of γ-valerolactone (GVL) via levulinic acid (LA) hydrogenation. A series of hyper-crosslinked porous polymer (HCP) supported Ru catalysts with different monomers were prepared. The wettabilities were controlled by the surface functional groups. The hydrophobic catalysts showed much higher activity than the hydrophilic ones in the hydrogenation of LA to GVL, highly possible due to the substrate enrichment. Further insight showed that the reaction proceeded through the 4-HVA route. These results illustrated the importance of surface wettability in bio-based molecule upgrading, which is beneficial for catalyst design.

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