Anodic substitution reaction of carbamates in a flow microreactor using a stable emulsion solution

Literature Information

Publication Date 2021-10-06
DOI 10.1039/D1RE00403D
Impact Factor 4.239
Authors

Rio Mikami, Yuto Nakamura, Naoki Shida, Mahito Atobe


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Abstract

An anodic substitution reaction in a flow microreactor using a stable emulsion solution prepared by tandem acoustic emulsification is demonstrated for the first time. The emulsion solution facilitated the selective anodic oxidation of carbamates, and the α-substituted products were ejected from the flow reactor to suppress overoxidation, resulting in an increase in the current efficiency for the desired reaction.

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Source Journal

Reaction Chemistry & Engineering

Reaction Chemistry & Engineering
CiteScore: 0
Self-citation Rate: 8.8%
Articles per Year: 284

Reaction Chemistry & Engineering is an interdisciplinary journal reporting cutting-edge research focused on enhancing the understanding and efficiency of reactions. Reaction engineering leverages the interface where fundamental molecular chemistry meets chemical engineering and technology. Challenges in chemistry can be overcome by the application of new technologies, while engineers may find improved solutions for process development from the latest developments in reaction chemistry. Reaction Chemistry & Engineering is a unique forum for researchers whose interests span the broad areas of chemical engineering and chemical sciences to come together in solving problems of importance to wider society. All papers should be written to be approachable by readers across the engineering and chemical sciences. Papers that consider multiple scales, from the laboratory up to and including plant scale, are particularly encouraged.

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