Single-nanoparticle spectroelectrochemistry studies enabled by localized surface plasmon resonance

Literature Information

Publication Date 2021-08-11
DOI 10.1039/D1CP02801D
Impact Factor 3.676
Authors

Shanlin Pan, Xiao Li, Jeetika Yadav


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Abstract

This review describes recent progress of spectroelectrochemistry (SEC) analysis of single metallic nanoparticles (NPs) which have strong surface plasmon resonance properties. Dark-field scattering (DFS), photoluminescence (PL), and electrogenerated chemiluminescence (ECL) are three commonly used optical methods to detect individual NPs and investigate their local redox activities in an electrochemical cell. These SEC methods are highly dependent on a strong light-scattering cross-section of plasmonic metals and their electrocatalytic characteristics. The surface chemistry and the catalyzed reaction mechanism of single NPs and their chemical transformations can be studied using these SEC methods. Recent progress in the experimental design and fundamental understanding of single-NP electrochemistry and catalyzed reactions using DFS, PL, and ECL is described along with selected examples from recent publications in this field. Perspectives on the challenges and possible solutions for these SEC methods and potential new directions are discussed.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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