Solvent-controlled assembly of pillar[5]arene-based supramolecular networks via π–π interactions for white light modulation
Literature Information
Publication Date
2019-12-13
DOI
10.1039/C9QO01383K
Impact Factor
5.281
Authors
Qi Li, Yuezhou Liu, Peiren Liu, Liqing Shangguan, Huangtianzhi Zhu, Bingbing Shi
View Original
Abstract
White light emitting materials have gained considerable attention. Exploring new strategies to achieve controllable white light emission is important for the construction and application of fluorescent materials. Here we report a supramolecular network based on pyrene-containing pillar[5]arene via π–π interactions, whose assembly and emission are controlled by solvent polarity. By introducing a red emissive europium complex guest, we successfully fabricate a supramolecular crosslinked network with solvent polarity-dependent emissions. White light emission with a CIE coordinate at (0.33, 0.31) is also achieved by adjusting the methanol fraction. This work provides a method to construct tunable fluorescent supramolecular systems and generate homogeneous white light emission by controlling noncovalent interactions.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
Oxalic acid compound with cyclohexylsulfamothioic O-acid (11)
CAS Number:
31895-22-4
Molecular Formula:
C7H13NO4S3
2-Methyl-2-propanyl 4-iodo-1-piperidinecarboxylate
CAS Number:
301673-14-3
Molecular Formula:
C10H18INO2
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