Synthesis of an open-cage fullerene-based unidirectional H-bonding network and its coordination with titanium
Literature Information
Publication Date
2019-03-05
DOI
10.1039/C9QO00188C
Impact Factor
5.281
Authors
Hao Zhang, Jie Su, Changwang Pan, Xing Lu
View Original
Abstract
Open-cage fullerene derivatives with up to three hydroxyl groups on the rim of an orifice were prepared through modification of functional groups followed by controlled stepwise reduction of carbonyl groups on the rim. The hydroxyl groups form a unidirectional H-bond network and show a weak but clear interaction with a water molecule trapped inside the fullerene cage. Titanium ions coordinated with the hydroxyl and carbonyl groups to form a TiL2 type of complex.
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Organic Chemistry Frontiers
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