Cu(ii)- or Co(ii)-Catalyzed C(SP3)–H oxidation of N,N-dimethylaminoethanol: facile synthesis of methylene-bridged biindoles and 3-formylindoles selectively
Literature Information
Publication Date
2019-03-01
DOI
10.1039/C9QO00097F
Impact Factor
5.281
Authors
Robert C. Hider
View Original
Abstract
Methylene-bridged biindoles and 3-formylindoles were selectively synthesized using a new carbon donor N,N-dimethylethanolamine, catalyzed by CuCl2 and CoCl2 respectively. A high conversion rate and good regioselectivity were achieved. Oxygen atmosphere promoted the reaction toward the conversion of 3-formylindoles.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
![2,2'-{2,2-Propanediylbis[(2,6-dibromo-4,1-phenylene)oxy]}diethanol structure](https://static.chemtradehub.com/structs/416/4162-45-2-b3d6.webp "2,2'-{2,2-Propanediylbis[(2,6-dibromo-4,1-phenylene)oxy]}diethanol structure")
2,2'-{2,2-Propanediylbis[(2,6-dibromo-4,1-phenylene)oxy]}diethanol
CAS Number:
4162-45-2
Molecular Formula:
C19H20Br4O4
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