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Rhodium-catalyzed homodimerization–cyclization reaction of two vinyl isocyanides: a general route to 2-(isoquinolin-1-yl)oxazoles
Literature Information
Publication Date
2019-11-22
DOI
10.1039/C9QO01229J
Impact Factor
5.281
Authors
Zhuo Wang, Xiang-He Meng, Pei Liu, Wan-Ying Hu, Yu-Long Zhao
View Original
Abstract
A novel rhodium-catalyzed homodimerization–cyclization reaction of two vinyl isocyanides has been developed for the first time. In this reaction, the highly reactive 1,4-diazabutatriene intermediates generated by the homodimerization of two vinyl isocyanides could undergo a novel type of intramolecular tandem cyclization and provides a new and highly efficient method for the construction of 2-(isoquinolin-1-yl)oxazoles by formation of three new bonds and two rings from readily available acyclic starting materials in a single step.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
2-Methyl-2-propanyl 4-iodo-1-piperidinecarboxylate
CAS Number:
301673-14-3
Molecular Formula:
C10H18INO2
Oxalic acid compound with cyclohexylsulfamothioic O-acid (11)
CAS Number:
31895-22-4
Molecular Formula:
C7H13NO4S3
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