![2-{[4-(2-Methoxyethyl)phenoxy]methyl}oxirane structure](https://static.chemtradehub.com/structs/567/56718-70-8-f037.webp "2-{[4-(2-Methoxyethyl)phenoxy]methyl}oxirane structure")
Ruthenium(ii)-catalyzed C–O/C–S cyclization for the synthesis of 5-membered O-containing and S-containing heterocycles
Literature Information
Publication Date
2019-02-06
DOI
10.1039/C8QO01425F
Impact Factor
5.281
Authors
Jian Liu, Yu Wen, Fengjun He, Liang Gao, Lina Gao, Junwei Wang, Xiachang Wang, Yinan Zhang, Lihong Hu
View Original
Abstract
An efficient and convenient method for the synthesis of oxazole derivatives from enamides has been established via a ruthenium-catalyzed C–O cyclization. This protocol allows for a wide functional group compatibility, broad substrate scope and ease of operation. This catalytic method is also applicable to other 5-membered O-containing and S-containing heterocyclic systems involving thiazole and furan scaffolds, thus this strategy can be broadly applied to organic synthesis and medicinal chemistry.
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Source Journal
Organic Chemistry Frontiers
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7.8
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8.7%
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