A free-radical-promoted stereospecific denitro silylation of β-nitroalkenes with silanes
Literature Information
Publication Date
2019-08-21
DOI
10.1039/C9QO00819E
Impact Factor
5.281
Authors
Xi Zhang, Ming-Xia Liu, Tong-Lin Wang, Yong-Qing Wang, Xi-Cun Wang, Zheng-Jun Quan
View Original
Abstract
A Cu-catalyzed stereospecific denitro silylation of β-nitroalkenes with silanes for the synthesis of vinylsilanes using DTBP as the oxidant was developed. This method presented an inexpensive and non-toxic catalytic system with an appropriate substrate scope. This approach is (E)-specific and produced an important class of vinylsilanes in good yields.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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trans-2-{[(Tert-butoxy)carbonyl]amino}cyclobutane-1-carboxylic acid
CAS Number:
951173-25-4
Molecular Formula:
C10H17NO4
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Molecular Formula:
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