Ion speciation: a key for the understanding of the solution properties of ionic liquid mixtures
Literature Information
Kiki Adi Kurnia, Ana M. Fernandes, João A. P. Coutinho
Recently, combinations of two (or more) ionic liquids, known as ionic liquid mixtures, have become popular and have a broad range of applications. However, the fundamental knowledge on the molecular interactions that exist in ionic liquid mixtures is far from being understood. In this work, the experimental measurement of the water activity coefficient and computational modelling using Conductor-like Screening Model for Real Solvent (COSMO-RS) were carried out to get an insight into the molecular interactions that are present in ionic liquid mixtures in aqueous solution. The results show that the combination of two ionic liquids of different basicity in aqueous solution allows fine tuning of the water activities, covering a wide range of values that could replace several pure fluids. This is an important feature resulting from the unexpected ion speciation of the ionic liquid mixtures in aqueous solution.
Recommended Journals

Chemical Communications

Russian Journal of General Chemistry

Russian Journal of Bioorganic Chemistry

Saudi Pharmaceutical Journal

Journal of Peptide Science

Current Opinion in Solid State & Materials Science

Russian Journal of Applied Chemistry

Russian Chemical Bulletin

Journal of Natural Medicines

Journal of Saudi Chemical Society
Related Literature
Fmoc–RGDS based fibrils: atomistic details of their hierarchical assembly
David Zanuy, Jordi Poater, Miquel Solà, Ian W. Hamley
DOI: 10.1039/C5CP04269K
Light harvesting in photonic crystals revisited: why do slow photons at the blue edge enhance absorption?
O. Deparis, S. R. Mouchet, B.-L. Su
DOI: 10.1039/C5CP04983K
Interactions of hydrogen with the iron and iron carbide interfaces: a ReaxFF molecular dynamics study
Chenyu Zou, Sumathy Raman
DOI: 10.1039/C5CP06108C
High-performance formaldehyde gas-sensors based on three dimensional center-hollow ZnO
Linqi Shi, Jiabao Cui, Fei Zhao, Dejun Wang, Tengfeng Xie, Yanhong Lin
DOI: 10.1039/C5CP05935F
Adsorption of O2 on anionic silver clusters: spins and electron binding energies dominate in the range up to nano sizes
Jun Ma, Xizi Cao, Xiaopeng Xing, Xuefeng Wang, Joel H. Parks
DOI: 10.1039/C5CP06116D
Theoretical modeling of the L2,3-edge X-ray absorption spectra of Mn(acac)2 and Co(acac)2 complexes‡
Silvia Carlotto, Mauro Sambi, Andrea Vittadini
DOI: 10.1039/C5CP06844D
Electronic coherence and the kinetics of inter-complex energy transfer in light-harvesting systems
Pengfei Huo, Thomas F. Miller III
DOI: 10.1039/C5CP02517F
Spectroscopic evidence of ‘jumping and pecking’ of cholinium and H-bond enhanced cation–cation interaction in ionic liquids
Anne Knorr, Koichi Fumino, Anne-Marie Bonsa
DOI: 10.1039/C5CP03412D
An EPR study of ampullosporin A, a medium-length peptaibiotic, in bicelles and vesicles
Annalisa Dalzini, Fernando Formaggio, Claudio Toniolo, Marina Gobbo, Anna Lisa Maniero
DOI: 10.1039/C5CP04136H
You might also like
Is 6-(3-Fluorophenyl)picolinic acid (CAS: 887982-40-3) safe?
6-(3-Fluorophenyl)picolinic acid is generally considered safe for laboratory use...
What industries use (3R)-3-Pyrrolidinol (CAS: 2799-21-5)?
(3R)-3-Pyrrolidinol is used in the pharmaceutical industry as a precursor for dr...
What precautions should be taken when handling (4R,5R)-4,5-Diethoxycarbonyl-2,2-dimethyldioxolane (CAS: 59779-75-8)?
When handling (4R,5R)-4,5-Diethoxycarbonyl-2,2-dimethyldioxolane (CAS: 59779-75-...
How is 1-(6-Chloroimidazo[1,2-b]pyridazin-3-yl)ethanone (CAS: 90734-71-7) typically synthesized?
1-(6-Chloroimidazo[1,2-b]pyridazin-3-yl)ethanone is often synthesized via a mult...
What is the market or research trend for N-Ethyl-3,4-dimethylbenzylamine (CAS: 39180-83-1)?
The market for N-Ethyl-3,4-dimethylbenzylamine (CAS: 39180-83-1) remains steady,...
What is Tert-butyl 3-(pyrrolidin-1-yl)azetidine-1-carboxylate (CAS: 1019008-21-9)?
Tert-butyl 3-(pyrrolidin-1-yl)azetidine-1-carboxylate is a chemical compound wit...
What regulatory guidelines apply to 1-Bromo-3-chloro-2,4-dimethoxybenzene (CAS: 1228956-93-1)?
1-Bromo-3-chloro-2,4-dimethoxybenzene (CAS: 1228956-93-1) falls under the classi...
Is 8-Bromo-2-methyl-3,4-dihydroisoquinolin-1(2H)-one (CAS: 1368622-07-4) safe?
The safety of 8-Bromo-2-methyl-3,4-dihydroisoquinolin-1(2H)-one (CAS: 1368622-07...
Is Benzyl [(3S)-2,6-dioxo-3-piperidinyl]carbamate (CAS: 22785-43-9) safe?
Benzyl [(3S)-2,6-dioxo-3-piperidinyl]carbamate is generally safe when handled wi...
How should 1-{[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]sulfonyl}pyrrolidine (CAS: 928657-21-0) be stored?
1-{[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]sulfonyl}pyrrolidine s...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.




![4-[(2,4-Dihydroxyphenyl)diazenyl]-5-hydroxy-2,7-naphthalenedisulfonic acid structure 4-[(2,4-Dihydroxyphenyl)diazenyl]-5-hydroxy-2,7-naphthalenedisulfonic acid structure](https://static.chemtradehub.com/structs/362/3627-01-8-79ac.webp)