Cobalt-catalyzed condensation of sulfonyl azides with o-diisocyanoarenes and anilines: a new approach to N-sulfonyl guanidines
Literature Information
Publication Date
2019-08-20
DOI
10.1039/C9QO00815B
Impact Factor
5.281
Authors
Jin-Ming Yang, Rong Zhang, Shun-Yi Wang, Shun-Jun Ji
View Original
Abstract
A novel method for the synthesis of N-sulfonyl guanidines is reported using a cobalt-catalyzed cascade reaction of sulfonyl azides with o-diisocyanoarenes and anilines. Co(III)-nitrene is easily generated from a Co(II) complex and a sulfonyl azide and further reacts with o-diisocyanoarenes and anilines. In this multicomponent reaction, o-diisocyanoarenes serve as C1 building blocks, instead of engaging in a dual insertion process, allowing for the construction of N-sulfonyl guanidines.
Recommended Journals
Saudi Pharmaceutical Journal
Chemistry Education Research and Practice
Nature Medicine
Russian Journal of Coordination Chemistry
Current Opinion in Solid State & Materials Science
Chemical Communications
Russian Journal of General Chemistry
Drug Discovery Today
Journal of Natural Medicines
Journal of Saudi Chemical Society
Related Literature
Pulse radiolysis study on the reactivity of NO3˙ radical toward uranous(iv), hydrazinium nitrate and hydroxyl ammonium nitrate at room temperature and at 45 °C
R. Musat, J. L. Marignier, C. Le Naour, S. Denisov, L. Venault, Ph. Moisy, M. Mostafavi
2020-02-13
Paper
DOI: 10.1039/C9CP07034F
Comparison study of carbon clusters formation during thermal decomposition of 1,3,5-triamino-2,4,6-trinitrobenzene and benzotrifuroxan: a ReaxFF based sequential molecular dynamics simulation
Xuefeng Zhao, Xinping Long, Xiaogan Dai, Kaili Zhang, Ming Li, Feng Guo, Zhiqiang Qiao, Yushi Wen
2020-01-22
Paper
DOI: 10.1039/C9CP05734J
Pyridine–acetaldehyde, a molecular balance to explore the n→π* interaction
Susana Blanco, Alberto Macario, Juan Carlos López
2019-09-06
Communication
DOI: 10.1039/C9CP04088A
A ReaxFF molecular dynamics study of molecular-level interactions during binder jetting 3D-printing
Yawei Gao, Yun Kyung Shin, Daniel Martinez, Guha Manogharan, Adri C. T. van Duin
2019-09-10
Paper
DOI: 10.1039/C9CP03585K
Porous, n–p type ultra-long, ZnO@Bi2O3 heterojunction nanorods - based NO2 gas sensor: new insights towards charge transport characteristics
Vishnuraj Ramakrishnan, Keerthi G. Nair, Jayaseelan Dhakshinamoorthy, K. R. Ravi, Biji Pullithadathil
2020-03-04
Paper
DOI: 10.1039/D0CP00567C
Ground and excited state properties of furanoflavylium derivatives
Alfonso Alejo-Armijo, Nuno Basílio, Adilson A. Freitas, António L. Maçanita, João C. Lima, A. Jorge Parola, Fernando Pina
2019-09-13
Paper
DOI: 10.1039/C9CP04917G
Seeking minimum entropy production for a tree-like flow-field in a fuel cell
Marco Sauermoser, Signe Kjelstrup, Bruno G. Pollet, Eirik G. Flekkøy
2020-03-18
Paper
DOI: 10.1039/C9CP05394H
Charge compensation weakening ionized impurity scattering and assessing the minority carrier contribution to the Seebeck coefficient in Pb-doped Mg3Sb2 compounds
Qiang Zhang, Jichong Hou, Jianfeng Fan, Shaoping Chen, Wenhao Fan, Hua Zhang, Wenxian Wang, Yucheng Wu, Bingshe Xu
2020-03-11
Paper
DOI: 10.1039/D0CP00266F
You might also like
Compound Q&A
Is 6-(3-Fluorophenyl)picolinic acid (CAS: 887982-40-3) safe?
6-(3-Fluorophenyl)picolinic acid is generally considered safe for laboratory use...
887982-40-36-(3-Fluorophenyl)pi...
Compound Q&A
What industries use (3R)-3-Pyrrolidinol (CAS: 2799-21-5)?
(3R)-3-Pyrrolidinol is used in the pharmaceutical industry as a precursor for dr...
2799-21-5(3R)-3-Pyrrolidinol
Compound Q&A
What precautions should be taken when handling (4R,5R)-4,5-Diethoxycarbonyl-2,2-dimethyldioxolane (CAS: 59779-75-8)?
When handling (4R,5R)-4,5-Diethoxycarbonyl-2,2-dimethyldioxolane (CAS: 59779-75-...
59779-75-8(4R,5R)-4,5-Diethoxy...
Compound Q&A
How is 1-(6-Chloroimidazo[1,2-b]pyridazin-3-yl)ethanone (CAS: 90734-71-7) typically synthesized?
1-(6-Chloroimidazo[1,2-b]pyridazin-3-yl)ethanone is often synthesized via a mult...
90734-71-71-(6-Chloroimidazo[1...
Compound Q&A
What is the market or research trend for N-Ethyl-3,4-dimethylbenzylamine (CAS: 39180-83-1)?
The market for N-Ethyl-3,4-dimethylbenzylamine (CAS: 39180-83-1) remains steady,...
39180-83-1N-Ethyl-3,4-dimethyl...
Compound Q&A
What is Tert-butyl 3-(pyrrolidin-1-yl)azetidine-1-carboxylate (CAS: 1019008-21-9)?
Tert-butyl 3-(pyrrolidin-1-yl)azetidine-1-carboxylate is a chemical compound wit...
1019008-21-9Tert-butyl 3-(pyrrol...
Compound Q&A
What regulatory guidelines apply to 1-Bromo-3-chloro-2,4-dimethoxybenzene (CAS: 1228956-93-1)?
1-Bromo-3-chloro-2,4-dimethoxybenzene (CAS: 1228956-93-1) falls under the classi...
1228956-93-11-Bromo-3-chloro-2,4...
Compound Q&A
Is 8-Bromo-2-methyl-3,4-dihydroisoquinolin-1(2H)-one (CAS: 1368622-07-4) safe?
The safety of 8-Bromo-2-methyl-3,4-dihydroisoquinolin-1(2H)-one (CAS: 1368622-07...
1368622-07-48-Bromo-2-methyl-3,4...
Compound Q&A
Is Benzyl [(3S)-2,6-dioxo-3-piperidinyl]carbamate (CAS: 22785-43-9) safe?
Benzyl [(3S)-2,6-dioxo-3-piperidinyl]carbamate is generally safe when handled wi...
22785-43-9Benzyl [(3S)-2,6-dio...
Compound Q&A
How should 1-{[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]sulfonyl}pyrrolidine (CAS: 928657-21-0) be stored?
1-{[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]sulfonyl}pyrrolidine s...
928657-21-01-{[4-(4,4,5,5-Tetra...
Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
![(3R,4aR,7aS,9aR,10S,11R,13aR,13bS,15aS,15bR)-3,11-Dihydroxy-10-(hydroxymethyl)-4,4,7a,10,13a,15b-hexamethyl-1,2,3,4,4a,7,7a,8,9,9a,10,11,12,13,13a,13b,14,15,15a,15b-icosahydro-5H-naphtho[2',1':4,5]cyc
lohepta[1,2-a]naphthalen-5-one structure](https://static.chemtradehub.com/structs/538/53800-21-8-9f18.webp "(3R,4aR,7aS,9aR,10S,11R,13aR,13bS,15aS,15bR)-3,11-Dihydroxy-10-(hydroxymethyl)-4,4,7a,10,13a,15b-hexamethyl-1,2,3,4,4a,7,7a,8,9,9a,10,11,12,13,13a,13b,14,15,15a,15b-icosahydro-5H-naphtho[2',1':4,5]cyc
lohepta[1,2-a]naphthalen-5-one structure")
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.