Pyridine–acetaldehyde, a molecular balance to explore the n→π* interaction
Literature Information
Susana Blanco, Alberto Macario, Juan Carlos López
The complex pyridine–acetaldehyde is formed through an n→π* interaction and a C–H⋯O contact. The acetaldehyde methyl group internal rotation induces a phase-locked intermolecular oscillation along the Bürgi–Dunitz coordinate. Surprisingly, this sort of molecular balance extracts energy through the n→π* interaction to reduce the size of the internal rotation barrier.
Recommended Journals

Chemical Communications

Drug Discovery Today

Current Opinion in Solid State & Materials Science

Organic Process Research & Development

Crystallography Reports

Russian Journal of Organic Chemistry

Russian Journal of Applied Chemistry

Nature Medicine

Current Opinion in Colloid & Interface Science

Acta Materialia
Related Literature
Probing electrode/electrolyte interfaces in situ by X-ray spectroscopies: old methods, new tricks
Robert S. Weatherup
DOI: 10.1039/C5CP04058B
S-doped mesoporous nanocomposite of HTiNbO5 nanosheets and TiO2 nanoparticles with enhanced visible light photocatalytic activity
Ruirui Han, Hongmei Ji, Tao Sun, Jin Zhao, Ningna Chen, Jing Chen, Xuefeng Guo, Wenhua Hou, Weiping Ding
DOI: 10.1039/C5CP06555K
Porous nanoarchitectures of spinel-type transition metal oxides for electrochemical energy storage systems
Min-Sik Park, Jeonghun Kim, Ki Jae Kim, Jong-Won Lee, Jung Ho Kim
DOI: 10.1039/C5CP05936D
LiNi0.5Mn1.5O4 high-voltage cathode coated with Li4Ti5O12: a hard X-ray photoelectron spectroscopy (HAXPES) study
Malte Sachs, Michael Gellert, Min Chen, Hans-Jörg Drescher, Stefan Renato Kachel, Han Zhou, Malte Zugermeier, Mihaela Gorgoi, Bernhard Roling, J. Michael Gottfried
DOI: 10.1039/C5CP03837E
The electrochemical oxidation of toluene catalysed by Co(ii) in N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide‡
S. Balaji, K. Kannan, I. S. Moon
DOI: 10.1039/C5CP04151A
High-performance formaldehyde gas-sensors based on three dimensional center-hollow ZnO
Linqi Shi, Jiabao Cui, Fei Zhao, Dejun Wang, Tengfeng Xie, Yanhong Lin
DOI: 10.1039/C5CP05935F
Order and disorder in quaternary atomic laminates from first-principles calculations
Martin Dahlqvist, Johanna Rosen
DOI: 10.1039/C5CP06021D
Adsorption of O2 on anionic silver clusters: spins and electron binding energies dominate in the range up to nano sizes
Jun Ma, Xizi Cao, Xiaopeng Xing, Xuefeng Wang, Joel H. Parks
DOI: 10.1039/C5CP06116D
Fabrication of superhydrophilic–underwater superoleophobic inorganic anti-corrosive membranes for high-efficiency oil/water separation
Luyan Liu, Chen Chen, Siyu Yang, Hua Xie, MaoGang Gong, Xiaoliang Xu
DOI: 10.1039/C5CP06305A
You might also like
Is 6-(3-Fluorophenyl)picolinic acid (CAS: 887982-40-3) safe?
6-(3-Fluorophenyl)picolinic acid is generally considered safe for laboratory use...
What industries use (3R)-3-Pyrrolidinol (CAS: 2799-21-5)?
(3R)-3-Pyrrolidinol is used in the pharmaceutical industry as a precursor for dr...
What precautions should be taken when handling (4R,5R)-4,5-Diethoxycarbonyl-2,2-dimethyldioxolane (CAS: 59779-75-8)?
When handling (4R,5R)-4,5-Diethoxycarbonyl-2,2-dimethyldioxolane (CAS: 59779-75-...
How is 1-(6-Chloroimidazo[1,2-b]pyridazin-3-yl)ethanone (CAS: 90734-71-7) typically synthesized?
1-(6-Chloroimidazo[1,2-b]pyridazin-3-yl)ethanone is often synthesized via a mult...
What is the market or research trend for N-Ethyl-3,4-dimethylbenzylamine (CAS: 39180-83-1)?
The market for N-Ethyl-3,4-dimethylbenzylamine (CAS: 39180-83-1) remains steady,...
What is Tert-butyl 3-(pyrrolidin-1-yl)azetidine-1-carboxylate (CAS: 1019008-21-9)?
Tert-butyl 3-(pyrrolidin-1-yl)azetidine-1-carboxylate is a chemical compound wit...
What regulatory guidelines apply to 1-Bromo-3-chloro-2,4-dimethoxybenzene (CAS: 1228956-93-1)?
1-Bromo-3-chloro-2,4-dimethoxybenzene (CAS: 1228956-93-1) falls under the classi...
Is 8-Bromo-2-methyl-3,4-dihydroisoquinolin-1(2H)-one (CAS: 1368622-07-4) safe?
The safety of 8-Bromo-2-methyl-3,4-dihydroisoquinolin-1(2H)-one (CAS: 1368622-07...
Is Benzyl [(3S)-2,6-dioxo-3-piperidinyl]carbamate (CAS: 22785-43-9) safe?
Benzyl [(3S)-2,6-dioxo-3-piperidinyl]carbamate is generally safe when handled wi...
How should 1-{[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]sulfonyl}pyrrolidine (CAS: 928657-21-0) be stored?
1-{[4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]sulfonyl}pyrrolidine s...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.




