More than a CO source: palladium-catalyzed carbonylative synthesis of butenolides from propargyl alcohols and TFBen
Literature Information
Publication Date
2019-07-19
DOI
10.1039/C9QO00779B
Impact Factor
5.281
Authors
Zhengjie Le, Jun Ying
View Original
Abstract
Palladium-catalyzed direct carbonylation of propargyl alcohols for the synthesis of butenolides has been achieved. This transformation employs benzene-1,3,5-triyl triformate (TFBen) as the CO source and provides a facile and straightforward access to various substituted butenolides in high yields (up to 85%). Notably, phloroglucinol as the decomposed product of TFBen promotes the formation of butenolides.
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Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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CAS Number:
1640971-60-3
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CAS Number:
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Molecular Formula:
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