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Photoinduced free radical promoted cationic polymerization 40 years after its discovery
Literature Information
Publication Date
2019-12-30
DOI
10.1039/C9PY01903K
Impact Factor
5.582
Authors
Mehmet Atilla Tasdelen, Jacques Lalevée, Yusuf Yagci
View Original
Abstract
This perspective article is prepared in the memory of Anthony Ledwith who discovered Free Radical Promoted Cationic Polymerization (FRPCP) as a versatile photoinitiating system for cationic polymerization about four decades ago. Mechanistically, distinct modes for the photochemical formation of electron donor radicals in the UV, Vis and NIR range that can be oxidized to reactive cations to initiate the cationic polymerization of oxiranes and vinyl monomers are discussed. The dual polymerization strategies that have been applied to combine FRPCP with the other modes of polymerization processes are presented.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
1,3-Bis(trimethylsilyl)-2lambda~4~-diazathia-1,2-diene
CAS Number:
18156-25-7
Molecular Formula:
C6H18N2SSi2
2-Bromo-1-(bromomethyl)-3-(trifluoromethyl)benzene
CAS Number:
1214372-35-6
Molecular Formula:
C8H5Br2F3
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