Influence of the average molar mass of poly(N-vinylpyrrolidone) on the dimensions and conductivity of silver nanowires
Literature Information
Franziska Eichler, Nelli Weiß, Ludwig Bormann, Dhriti S. Ghosh, Jannick M. Sonntag
We investigate the influence of the average molar mass (Mw) of the capping agent poly(N-vinylpyrrolidone) (PVP) on the conductivity of a silver nanowire (AgNW) network. During the polyol process, the chain length of PVP is known to influence the AgNW diameters and lengths. By altering the reaction temperature and time and using PVP of different chain lengths, we synthesized AgNWs with varying diameters, lengths and PVP coverage. The obtained plethora of AgNWs is the basis for conductivity investigations of networks made of AgNWs with a diameter of either 60 nm or 80 nm. The results show a negative influence of long-chain PVP on the conductivity of the subsequent network if 60 nm thick AgNWs are employed. Overall, we obtain well performing AgNW transparent electrodes on glass with RS = 24.4 Ω sq−1 at 85.5%T550nm.
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.














