Palladium(ii)-mediated rapid 11C-cyanation of (hetero)arylborons
Literature Information
Zhouen Zhang, Takashi Niwa, Yasuyoshi Watanabe
A palladium(II)-mediated rapid 11C-cyanation of (hetero)arylborons with [11C]NH4CN/NH3 has been developed using bench-stable and readily available reagents. The method showed excellent functional-group tolerance, and allowed the highly efficient synthesis of a wide range of [11C]cyanoarenes, including PET tracers for aromatase imaging. A mechanistic study of the 11C-cyanation suggests the instantaneous formation of a mono[11C]cyanopalladium(II) complex that reacts smoothly with arylborons.
Related Literature
Novel scroll peapod produced by spontaneous scrolling of graphene onto fullerene string
Shuqiong Xu, Hongjin Fu, Chengmao Zhang, Zonglei Gu, Danhui Zhang
DOI: 10.1039/C6CP00385K
Co-operative motion of multiple benzoquinone disks at the air–water interface
Jennifer E. Satterwhite-Warden, Dilip K. Kondepudi
DOI: 10.1039/C5CP04471E
Isothermal microcalorimetry as a tool to study solid–electrolyte interphase formation in lithium-ion cells
David S. Hall, Stephen L. Glazier, J. R. Dahn
DOI: 10.1039/C6CP01309K
A perylene bisimide derivative with pyrene and cholesterol as modifying structures: synthesis and fluorescence behavior
Gang Wang, Weina Wang, Rong Miao, Congdi Shang, Meixia He, Haonan Peng, Gang He, Yu Fang
DOI: 10.1039/C6CP01447J
Biexponential photon antibunching: recombination kinetics within the Förster-cycle in DMSO
Michael Vester, Andreas Grueter, Björn Finkler, Robert Becker, Gregor Jung
DOI: 10.1039/C6CP00718J
Silane-initiated nucleation in chemically active plasmas: validation of density functionals, mechanisms, and pressure-dependent variational transition state calculations
Junwei Lucas Bao, Donald G. Truhlar
DOI: 10.1039/C6CP00816J
Local electric fields and molecular properties in heterogeneous environments through polarizable embedding
Nanna Holmgaard List, Hans Jørgen Aagaard Jensen, Jacob Kongsted
DOI: 10.1039/C6CP00669H
Stable n-type doping of graphene via high-molecular-weight ethylene amines
Insu Jo, Joonhee Moon, Subeom Park, Jin San Moon, Won Bae Park, Jeong Soo Lee, Byung Hee Hong
DOI: 10.1039/C5CP03196F
Thermal optical non-linearity of nematic mesophase enhanced by gold nanoparticles – an experimental and numerical investigation
O. Kurochkin, Y. K. Murugesan, T. P. Bennett, G. D'Alessandro, Y. Reznikov, B. J. Tang, G. H. Mehl, M. Kaczmarek
DOI: 10.1039/C6CP00116E
Photo-induced oxidation of the uniquely liganded heme f in the cytochrome b6f complex of oxygenic photosynthesis
Adrien A. P. Chauvet, Rachna Agarwal, André al Haddad, Frank van Mourik, William A. Cramer
DOI: 10.1039/C6CP01592A
You might also like
What is the market or research trend for N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0)?
N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0) is increasingly being used ...
What precautions should be taken when handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate (CAS: 1050507-06-6)?
When handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate, appropriate p...
What regulatory guidelines apply to diethyldiselane (CAS: 628-39-7)?
Diethyldiselane (CAS: 628-39-7) is classified under the Globally Harmonized Syst...
What is the market or research trend for oxocopper (CAS: 12053-18-8)?
The market for oxocopper (CAS: 12053-18-8) is primarily driven by its use in cat...
What is the market or research trend for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-carboxylic acid?
The market for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-c...
What is 2-(1-Pyrrolidinyl)-4-pyridinamine (CAS: 35981-63-6)?
2-(1-Pyrrolidinyl)-4-pyridinamine is a chemical compound with the CAS number 359...
What are the physical and chemical properties of 2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1)?
2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1) is a crystalline sol...
How is (S)-Alpha-allyl-proline hydrochloride (CAS: 129704-91-2) typically synthesized?
(S)-Alpha-allyl-proline hydrochloride is usually synthesized via a Wittig reacti...
What is 3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5)?
3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5) is an organic compound w...
How is Lys-SMCC-DM1 (CAS: 1281816-04-3) typically synthesized?
Lys-SMCC-DM1 is synthesized via a multi-step process involving the coupling of S...
Source Journal
Organic & Biomolecular Chemistry

Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.












![1-(1-Benzyl-1,2,3,6-tetrahydropyridin-4-yl)-1H-benzo[d]imidazol-2(3H)-one structure 1-(1-Benzyl-1,2,3,6-tetrahydropyridin-4-yl)-1H-benzo[d]imidazol-2(3H)-one structure](https://static.chemtradehub.com/structs/603/60373-71-9-7dfb.webp)

![1-{3-[4-Amino-3-(4-phenoxyphenyl)-1H-pyrazolo[3,4-d]pyrimidin-1-yl]-1-piperidinyl}-2,3-dihydroxy-1-propanone structure 1-{3-[4-Amino-3-(4-phenoxyphenyl)-1H-pyrazolo[3,4-d]pyrimidin-1-yl]-1-piperidinyl}-2,3-dihydroxy-1-propanone structure](https://static.chemtradehub.com/structs/122/1226872-27-0-e037.webp)