Synthesis of α-oxygenated β,γ-unsaturated ketones by a catalytic rearrangement strategy
Literature Information
Luisa Lempenauer, Aline Soupart, Elisabet Duñach, Gilles Lemière
A straightforward two-step entry to α-oxgenated β,γ-unsaturated ketones from readily available α,β-unsaturated ketones is disclosed. It was found that bis(allylic) alcohols undergo a skeletal rearrangement in the presence of 1 mol% of cheap and non-corrosive p-toluenesulfonic acid. Computational studies were conducted to support the mechanism and to rationalise the influence of the catalyst acidity on the product selectivity.
Recommended Journals
Related Literature
Self-healable functional polymers based on Diels–Alder ‘click chemistry’ involving substituted furan and triazolinedione derivatives: a simple and very fast approach
Prantik Mondal, Gourhari Jana, Tuhin Subhra Pal, Nikhil K. Singha
DOI: 10.1039/D1PY00910A
Syndiospecific coordination (Co)polymerization of carbazole-substituted styrene derivatives using the scandium catalyst system
Xiaochun Mu, Yang Li
DOI: 10.1039/D1PY00896J
Polymer actuators based on covalent adaptable networks
Yahe Wu, Yan Ji
DOI: 10.1039/D0PY00075B
Intrinsic flame retardant phosphonate-based vitrimers as a recyclable alternative for commodity polymers in composite materials
Jens C. Markwart, Alexander Battig, Tobias Urbaniak, Katharina Haag, Katharina Koschek, Bernhard Schartel, Frederik R. Wurm
DOI: 10.1039/D0PY00275E
Alginate-based diblock polymers: preparation, characterization and Ca-induced self-assembly
Amalie Solberg, Ingrid V. Mo, Finn L. Aachmann, Christophe Schatz, Bjørn E. Christensen
DOI: 10.1039/D1PY00727K
Impacts of performing electrolysis during organocatalyzed atom transfer radical polymerization
Daniel A. Corbin, Blaine G. McCarthy, Garret M. Miyake
DOI: 10.1039/D0PY00643B
Multifunctional system for combined chemodynamic–photodynamic therapy employing the endothelin axis based on conjugated polymer nanoparticles
Khalaf A. Jasim, Ibrahim F. Waheed
DOI: 10.1039/D1PY00964H
High-performance polyamides with engineered disorder
Julien Cretenoud, Sandor Balog, Véronique Michaud, Jean-Marc Chenal, Olivier Lame, Christopher J. G. Plummer, Holger Frauenrath
DOI: 10.1039/D1PY01225H
You might also like
What is the market or research trend for N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0)?
N-(4-Methoxybenzyl)-2-pyridinamine (CAS: 52818-63-0) is increasingly being used ...
What precautions should be taken when handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate (CAS: 1050507-06-6)?
When handling Ethyl 4-(2-chlorophenyl)-1,3-thiazole-2-carboxylate, appropriate p...
What regulatory guidelines apply to diethyldiselane (CAS: 628-39-7)?
Diethyldiselane (CAS: 628-39-7) is classified under the Globally Harmonized Syst...
What is the market or research trend for oxocopper (CAS: 12053-18-8)?
The market for oxocopper (CAS: 12053-18-8) is primarily driven by its use in cat...
What is the market or research trend for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-carboxylic acid?
The market for 5-{[(2-Methyl-2-propanyl)oxy]carbonyl}-5-azaspiro[2.4]heptane-7-c...
What is 2-(1-Pyrrolidinyl)-4-pyridinamine (CAS: 35981-63-6)?
2-(1-Pyrrolidinyl)-4-pyridinamine is a chemical compound with the CAS number 359...
What are the physical and chemical properties of 2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1)?
2-(3-Pyridinyl)-1-azabicyclo[2.2.2]octane (CAS: 91556-75-1) is a crystalline sol...
How is (S)-Alpha-allyl-proline hydrochloride (CAS: 129704-91-2) typically synthesized?
(S)-Alpha-allyl-proline hydrochloride is usually synthesized via a Wittig reacti...
What is 3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5)?
3-Methyl-1,2-oxazole-5-carboxylic acid (CAS: 4857-42-5) is an organic compound w...
How is Lys-SMCC-DM1 (CAS: 1281816-04-3) typically synthesized?
Lys-SMCC-DM1 is synthesized via a multi-step process involving the coupling of S...
Source Journal
Organic & Biomolecular Chemistry

Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.










![1-[6-(1H-Imidazol-1-yl)-3-pyridinyl]methanamine structure 1-[6-(1H-Imidazol-1-yl)-3-pyridinyl]methanamine structure](https://static.chemtradehub.com/structs/914/914637-08-4-8825.webp)



