Unique homo–heterojunction synergistic system consisting of stacked BiOCl nanoplate/Zn–Cr layered double hydroxide nanosheets promoting photocatalytic conversion of CO2 into solar fuels

Literature Information

Publication Date 2018-04-20
DOI 10.1039/C8CC01873A
Impact Factor 6.222
Authors

Ruotian Chen, Xianguang Meng, Bihu Lv, Fengtao Fan, Jinhua Ye, Xiaoyong Wang, Can Li


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Abstract

A unique homo–heterojunction synergistic system consisting of stacked BiOCl nanoplate/Zn–Cr layered double hydroxide (Zn–Cr LDH) nanosheets was rationally constructed via a simple electrostatic interaction between them. The purposeful spatial isolation of the holes in the crystal facet-based BiOCl homojunction from the BiOCl/Zn–Cr LDH heterojunction interface significantly increased the survivability of the electrons crossing therein. The optimized loading of Zn–Cr LDH in the system is the prerequisite for the enhanced photoconversion efficiency of CO2.

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