On the kinetic decomposition voltage of ternary oxides

Literature Information

Publication Date 2018-01-08
DOI 10.1039/C7CP06009B
Impact Factor 3.676
Authors

Han-Ill Yoo


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Abstract

In a previous article the authors reported the kinetic unmixing and decomposition of the ternary oxide NiTiO3 by an externally applied voltage. It was found [J. Chun, et al., J. Appl. Phys., 117, 2015, 124504] that while kinetic unmixing occurred for all magnitudes of the applied voltage, kinetic decomposition occurred only above a certain threshold voltage Ukind. The experimentally determined value of Ukind, however, did not coincide with the thermodynamic expectation according to the definition by Gibbs (). In this work the kinetic decomposition voltage Ukind of a ternary oxide ABOν is theoretically derived and compared with the experimental results. It turns out that Ukind depends on the mobility ratio of the cations and agrees with observed results for the system of NiTiO3 within the error bounds.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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