Alternative approaches for the aqueous–organic biphasic hydroformylation of higher alkenes

Literature Information

Publication Date 2012-09-14
DOI 10.1039/C2CY20538F
Impact Factor 6.119
Authors

Lorenz Obrecht, Paul C. J. Kamer, Wouter Laan


View Original

Abstract

The biphasic hydroformylation of linear alkenes using the Rh–TPPTS catalyst system is one of the cornerstones of aqueous biphasic catalysis, but due to mass-transfer limitations its application is restricted to short alkenes. This perspective provides an overview of various alternative approaches which have been developed to extend the aqueous biphasic methodology to the hydroformylation of higher alkenes.

Related Literature

Flexible enzymatic and chemo-enzymatic approaches to a broad range of uridine-diphospho-sugars

James C. Errey, Balaram Mukhopadhyay, K. P. Ravindranathan Kartha, Robert A. Field

2004-10-13 Communication

DOI: 10.1039/B410184G

Palladium catalysed cyclisation–carbonylation of enynes to give cyclic γ,δ-unsaturated acids

Varinder K. Aggarwal, Mike Butters, Paul W. Davies

2003-04-02 Communication

DOI: 10.1039/B300719G

In situ magnetic resonance imaging of electrically-induced water diffusion in a Nafion ionic polymer film

Richard T. Baker, Leila Naji, Karen Lochhead, John A. Chudek

2003-03-18 Communication

DOI: 10.1039/B301039B

Selective growth of a less stable polymorph of 2-iodo-4-nitroaniline on a self-assembled monolayer template

Rupa Hiremath, Stephen W. Varney, Jennifer A. Swift

2004-10-15 Communication

DOI: 10.1039/B411649F

A two-step field-induced magnetic transition in a novel layered cobalt diphosphonate

Ping Yin, Song Gao, Li-Min Zheng, Zheming Wang, Xin-Quan Xin

2003-03-31 Communication

DOI: 10.1039/B212674E

Chiral self-dimerization of vanadium complexes on a SiO2 surface: the first heterogeneous catalyst for asymmetric 2-naphthol coupling

Mizuki Tada, Toshiaki Taniike, Lakshmi M. Kantam, Yasuhiro Iwasawa

2004-10-04 Communication

DOI: 10.1039/B410307F

Unusual chromic and doping behavior of ether substituted polythiophenes

Yu Wang, William B. Euler, Brett L. Lucht

2004-02-11 Communication

DOI: 10.1039/B312537H

Thermosensitive PNIPAAm cryogel with superfast and stable oscillatory properties

Xian-Zheng Zhang, Chih-Chang Chu

2003-05-19 Communication

DOI: 10.1039/B301423A

Facile protocol for the highly regioselective and stereodivergent synthesis of substituted bishomoallylic alcohols from esters

Martin Oestreich, Fernando Sempere-Culler

2004-02-17 Communication

DOI: 10.1039/B315758J

Selenocatalytic α-halogenation

Chao Wang, Jon Tunge

2004-10-07 Communication

DOI: 10.1039/B410576A

You might also like

Compound Q&A

What industries use (1R,3S)-1,3-Cyclopentanediol (CAS: 16326-97-9)?

(1R,3S)-1,3-Cyclopentanediol finds applications in various industries. In the ph...

16326-97-9(1R,3S)-1,3-Cyclopen...
Compound Q&A

What precautions should be taken when handling N'-[4-(Dimethylamino)phenyl]-N,N-dimethyl-1,4-benzenediamine (CAS: 637-31-0)?

When handling N'-[4-(Dimethylamino)phenyl]-N,N-dimethyl-1,4-benzenediamine, it i...

637-31-0N'-[4-(Dimethylamino...
Compound Q&A

Are there alternatives to 5-(2,4-Difluorophenyl)-2-methoxypyrimidine (CAS: 1352318-16-1) in synthesis?

There are several alternatives to 5-(2,4-Difluorophenyl)-2-methoxypyrimidine in ...

1352318-16-15-(2,4-Difluoropheny...
Compound Q&A

What regulatory guidelines apply to 1-(3-Methoxyphenoxy)propan-2-ol (CAS: 382141-68-6)?

1-(3-Methoxyphenoxy)propan-2-ol (CAS: 382141-68-6) must comply with the Globally...

382141-68-61-(3-Methoxyphenoxy)...
Compound Q&A

Is Tetrodotoxin Citrate (CAS: 18660-81-6) safe?

Tetrodotoxin Citrate is extremely dangerous and should be handled with extreme c...

18660-81-6Tetrodotoxin Citrate
Compound Q&A

What are the main uses of 2-Methyl-2-propanyl [(1R,3S)-3-hydroxycyclopentyl]carbamate (CAS: 225641-84-9)?

2-Methyl-2-propanyl [(1R,3S)-3-hydroxycyclopentyl]carbamate (CAS: 225641-84-9) i...

225641-84-92-Methyl-2-propanyl ...
Compound Q&A

How should waste containing 4-(2-Hydroxyhexafluoroisopropyl)Benzoic Acid (CAS: 16261-80-6) be handled?

Waste containing 4-(2-Hydroxyhexafluoroisopropyl)Benzoic Acid (CAS: 16261-80-6) ...

16261-80-64-(2-Hydroxyhexafluo...
Compound Q&A

How is 2-Methyl-2-proanyl {(2S)-1-[(benzyloxy)amino]-3-hydroxy-3-methyl-1-oxo-2-butanyl}carbamate (CAS: 102507-19-7) typically synthesized?

2-Methyl-2-proanyl {(2S)-1-[(benzyloxy)amino]-3-hydroxy-3-methyl-1-oxo-2-butanyl...

102507-19-72-Methyl-2-propanyl ...
Compound Q&A

What is Benzeneethanamine, α-ethyl-, hydrochloride (1:1) (CAS: 20735-15-3)?

Benzeneethanamine, α-ethyl-, hydrochloride (1:1) is an organic compound with the...

20735-15-3Benzeneethanamine, α...
Compound Q&A

Are there alternatives to 3-{(E)-[4-(Dimethylamino)phenyl]diazenyl}benzoic acid (CAS: 20691-84-3) in synthesis?

In the synthesis of compounds similar to 3-{(E)-[4-(Dimethylamino)phenyl]diazeny...

20691-84-33-{(E)-[4-(Dimethyla...

Source Journal

Catalysis Science & Technology

Catalysis Science & Technology
CiteScore: 5.91
Self-citation Rate: 4.5%
Articles per Year: 600

Catalysis Science & Technology is committed to publishing research reporting high-quality, cutting-edge developments across the catalysis community at large. The journal places equal focus on publications from the heterogeneous, homogeneous, thermo-, electro-, photo-, organo- and biocatalysis communities. Works published in the journal feature a balanced mix of fundamental, technology-oriented, experimental, computational, digital and data-driven original research, thus appealing to catalysis practitioners in both academic and industrial environments. Original research articles published in the journal must demonstrate new catalytic discoveries and/or methodological advances that represent a significant advance on previously published work, from the molecular to the process scales. We welcome rigorous research in a wide range of timely or emerging applications related to the environment, health, energy and materials. Catalysis Science & Technology publishes Communications, Articles, Reviews and Perspectives. More details regarding manuscript types may be found in the Information for Authors section.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.