Secondary phosphineoxides as pre-ligands for nanoparticle stabilization

Literature Information

Publication Date 2012-12-12
DOI 10.1039/C2CY20683H
Impact Factor 6.119
Authors

Eoin Rafter, Florian Löw, Gerd Buntkowsky, Bruno Chaudret, Piet W. N. M. van Leeuwen


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Abstract

The synthesis of ruthenium nanoparticles (RuNPs) using secondary phosphine oxides (SPOs) as ligands is reported. These easily accessible ligands allow the formation of small nanoparticles in the size range of 1–2 nm which display a high efficiency for hydrogenation of aromatics with TOFs up to 2700 mol h−1.

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Catalysis Science & Technology

Catalysis Science & Technology
CiteScore: 5.91
Self-citation Rate: 4.5%
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