Highly sensitive electrical detection of TCNE on chemically passivated silicon-on-insulator‡
Literature Information
Publication Date
2011-09-05
DOI
10.1039/C1CC12504D
Impact Factor
6.222
Authors
Federico Rosei, Gregory P. Lopinski
View Original
Abstract
Adsorption of tetracyanoethylene (TCNE) onto hydrogen terminated, n-type silicon-on-insulator is shown to cause significant depletion of majority carriers. Employing an ambient pseudo-MOSFET, ppm levels of TCNE vapour rapidly decrease the n-channel saturation current by at least two orders of magnitude. Covalent passivation with a decyl monolayer improves the reversibility of the response while only slightly decreasing the sensitivity.
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