The role of liquid–liquid transition in glass formation of CuZr alloys
Literature Information
Xi Zhao, Chunzhen Wang, Haijiao Zheng, Zean Tian, Lina Hu
Some glass-forming liquids have different liquid phases that have the same composition but different structure, density and entropy. Based on experimental and molecular dynamics simulation, we here report thermodynamic, dynamic, and structural evidence of the liquid–liquid transition (LLT) in ten Cu–Zr glass-forming liquids well above the liquidus temperature. We find that for Cu–Zr alloys, the LLT is beneficial to glass formation, and there is a close relationship between the relative transition strength (RTS) of the LLT and the critical thickness representing the glass forming ability (GFA): the bigger the value of the RTS parameters, the stronger the GFA of Cu–Zr alloys. This work not only uncovers the role of the LLT of melts in the glass formation of solids, but also sheds light on the inheritance of properties of glassy solids from the aspect of the detectable dynamics of high-temperature melts.
Recommended Journals

Current Opinion in Solid State & Materials Science

Current Opinion in Colloid & Interface Science

Russian Chemical Bulletin

New Journal of Chemistry

Russian Journal of General Chemistry

Chemistry Education Research and Practice

Russian Journal of Bioorganic Chemistry

Russian Journal of Coordination Chemistry

Chemical Communications

Drug Discovery Today
Related Literature
Highly selective CO2 separation membranes through tunable poly(4-vinylphenolate)–CO2 interactions
Markus Hammann, Dante Castillo, Christian Anger, Bernhard Rieger
DOI: 10.1039/C4TA03696D
Barrierless photoisomerisation of the “simplest cyanine”: Joining computational and femtosecond optical spectroscopies to trace the full reaction path
Alexander Weigel, Matthias Pfaffe, Mohsen Sajadi, Rainer Mahrwald, Roberto Improta, Vincenzo Barone, Dario Polli, Giulio Cerullo, Nikolaus P. Ernsting, Fabrizio Santoro
DOI: 10.1039/C2CP41522D
Glyoxylamide-based self-assembly hydrogels for sustained ciprofloxacin delivery
Vina R. Aldilla, Shashidhar Nizalapur, Christopher E. Marjo, Anne M. Rich, Kitty K. K. Ho, David StC. Black
DOI: 10.1039/C8TB01290C
Effects of melt aging and off-stoichiometric melts on CsSrI3:Eu2+ single crystal scintillators
Merry Koschan
DOI: 10.1039/C6CP00271D
Film morphology evolution during solvent vapor annealing of highly efficient small molecule donor/acceptor blends
Sebastian Engmann, Hyun Wook Ro, Andrew Herzing, Chad R. Snyder, Lee J. Richter, Paul B. Geraghty, David J. Jones
DOI: 10.1039/C6TA05056E
Synthesis, properties and applications of flowerlike Ni–NiO composite microstructures
Feifei Yuan, Yonghong Ni, Li Zhang, Shengmei Yuan, Jieding Wei
DOI: 10.1039/C3TA11219E
The structure of chromophore-grafted amyloid-β12–28 dimers in the gas-phase: FRET-experiment guided modelling
DOI: 10.1039/C6CP00263C
Industrial feasibility of anodic hydrogen peroxide production through photoelectrochemical water splitting: a techno-economic analysis
Kasper Wenderich, Wouter Kwak, Alexa Grimm, Gert Jan Kramer, Guido Mul, Bastian Mei
DOI: 10.1039/D0SE00524J
Microwave-assisted simultaneous reduction and titanate treatment of graphene oxide
Jing Li, Zhenzhen Yang, Hanxun Qiu, Yigang Dai, Qingbin Zheng, Guang-Ping Zheng, Junhe Yang
DOI: 10.1039/C3TA12228J
You might also like
Are there alternatives to 1-(4-Chlorophenyl)-N-hydroxymethanimine (CAS: 3848-36-0) in synthesis?
When considering alternatives to 1-(4-Chlorophenyl)-N-hydroxymethanimine (CAS: 3...
How should (1R,9S,10S,12S,14E,16S,19R,20R,21S,22R)-3,9,21-Trihydroxy-5,10,12,14,16,20,22-heptamethyl-23,24-dioxatetracyclo[17.3.1.1~6,9~.0~2,7~]tetracosa-2,5,7,14-tetraen-4-one (CAS: 183202-73-5) be stored?
This compound should be stored in a cool, dry place away from direct sunlight. I...
How is 3-(4-Bromophenyl)-5-(2-fluorophenyl)-1,2,4-oxadiazole (CAS: 419553-16-5) typically synthesized?
3-(4-Bromophenyl)-5-(2-fluorophenyl)-1,2,4-oxadiazole is synthesized through a m...
How is 5-Chloro-2-(4-chlorophenyl)-4-methyl-6-[3-(1-piperidinyl)propoxy]pyrimidine (CAS: 1639220-19-1) typically synthesized?
5-Chloro-2-(4-chlorophenyl)-4-methyl-6-[3-(1-piperidinyl)propoxy]pyrimidine (CAS...
What industries use 2-Chloro-4-(difluoromethoxy)pyridine (CAS: 1206978-15-5)?
2-Chloro-4-(difluoromethoxy)pyridine is used in the pharmaceutical industry for ...
What regulatory guidelines apply to 3-Chloro-6-methylpyridazine (CAS: 1121-79-5)?
3-Chloro-6-methylpyridazine (CAS: 1121-79-5) is classified under the Globally Ha...
Are there alternatives to Methyl 4,5-dimethyl-2-nitrobenzoate in synthesis?
Several alternatives can be used in the synthesis of Methyl 4,5-dimethyl-2-nitro...
Are there alternatives to (2E,2'E)-3,3'-(1,4-Phenylene)bisacrylaldehyde in synthesis?
Alternatives to (2E,2'E)-3,3'-(1,4-Phenylene)bisacrylaldehyde include other acry...
What is 3-Amino-5-chloropyridin-2-ol hydrochloride (CAS: 1261906-29-9)?
3-Amino-5-chloropyridin-2-ol hydrochloride is an organic compound with the CAS n...
What precautions should be taken when handling 6,7-Difluoro-2,3-dihydro-4H-chromen-4-one (CAS: 1092349-93-3)?
When handling 6,7-Difluoro-2,3-dihydro-4H-chromen-4-one, it is essential to wear...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.
![4-[(3-Chloro-2-fluorophenyl)amino]-7-methoxy-6-quinazolinyl acetate structure 4-[(3-Chloro-2-fluorophenyl)amino]-7-methoxy-6-quinazolinyl acetate structure](https://static.chemtradehub.com/structs/740/740081-22-5-f58f.webp)



