Ru-Catalyzed selective C–H oxidative olefination with N-heteroarenes directed by pivaloyl amide
Literature Information
Publication Date
2016-08-08
DOI
10.1039/C6QO00327C
Impact Factor
5.281
Authors
Li Zhang, Changpeng Chen, Jian Han, Zhi-Bin Huang, Yingsheng Zhao
View Original
Abstract
A highly efficient and practical Ru-catalyzed direct C–H functionalization of indolines and N-alkylaniline with a simple pivaloyl as a directing group is developed. Broad substrate scopes with respect to N-heteroarenes and olefins are observed. The selective C7-position alkynylation for indoline also proceeds well by using inexpensive ruthenium as a catalyst, and pivaloyl as a directing group.
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8.7%
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Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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